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Acceleration of Acetone Destruction Process under Synergistic Action of Photocatalytic Oxidation and Barrier Discharge Full article

Journal Plasma Chemistry and Plasma Processing
ISSN: 0272-4324 , E-ISSN: 1572-8986
Output data Year: 2007, Volume: 27, Number: 5, Pages: 624-634 Pages count : 11 DOI: 10.1007/s11090-007-9090-2
Tags Air purification, Decomposition, Decontamination, Photocatalysis, Surface barrier discharge
Authors Besov Alexey S. 1 , Vorontsov Alexander V. 2
Affiliations
1 Boreskov Institute of Catalysis, pr. Ak. Lavrentieva 5, Novosibirsk 630090, Russian Federation
2 Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russian Federation

Abstract: Separate and joint work of photocatalytic oxidation based on TiO2 and surface barrier discharge as a source of active oxygen and UV radiation is investigated for acetone vapors destruction under ambient air conditions. Experiments were carried out in a 404 l airtight Plexiglas chamber and used five different combinations of photocatalyst, barrier discharge and ultraviolet irradiation under identical initial concentration (∼170 ppm) of acetone. It is shown for the synergistic action of photocatalytic method and barrier discharge that the initial rate of acetone decomposition per watt of input power increases in more than 1.5 times compared to photocatalytic oxidation. Under operation of plasma of barrier discharge, intermediate products are formed such as CO, acetic acid, acetaldehyde and methane nitrate (CH3NO3). These products are not detected for photocatalytic oxidation. Some interesting features of kinetics of acetone decomposition and formation of intermediate products with participation of barrier discharge are revealed.
Cite: Besov A.S. , Vorontsov A.V.
Acceleration of Acetone Destruction Process under Synergistic Action of Photocatalytic Oxidation and Barrier Discharge
Plasma Chemistry and Plasma Processing. 2007. V.27. N5. P.624-634. DOI: 10.1007/s11090-007-9090-2 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Apr 5, 2007
Accepted: Jun 22, 2007
Published online: Jul 26, 2007
Published print: Oct 1, 2007
Identifiers:
Web of science: WOS:000249270500009
Scopus: 2-s2.0-34548385618
Elibrary: 13551118
Chemical Abstracts: 2007:986047
Chemical Abstracts (print): 147:507215
OpenAlex: W2162241121
Citing:
DB Citing
Web of science 17
Scopus 19
Elibrary 18
OpenAlex 18
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