Mechanism of β-Picoline Oxidation to Nicotinic Acid on V-Ti-O Catalyst as Studied by in situ FTIR Full article
| Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
||
|---|---|---|---|
| Output data | Year: 2006, Volume: 87, Number: 2, Pages: 387-394 Pages count : 8 DOI: 10.1007/s11144-006-0047-x | ||
| Tags | β-picoline, In situ FTIR spectroscopy, Intermediate, Nicotinic acid, V-Ti-O catalyst | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
In situ FTIR spectroscopy was used to study the interaction of beta-picoline with the surface of a V-Ti-O catalyst in the temperature range of 120-300°C. Beta-picoline was found to react with the Lewis acid sites of the catalyst to form a nitrogen-coordinated complex. This complex turns into an aldehyde-like complex at 150-250°C and then into a nicotinate, which is a direct precursor of nicotinic acid.
Cite:
Popova G.Y.
, Andrushkevich T.V.
, Chesalov Y.A.
, Ovchinnikova E.V.
Mechanism of β-Picoline Oxidation to Nicotinic Acid on V-Ti-O Catalyst as Studied by in situ FTIR
Reaction Kinetics and Catalysis Letters. 2006. V.87. N2. P.387-394. DOI: 10.1007/s11144-006-0047-x WOS Scopus РИНЦ ANCAN OpenAlex
Mechanism of β-Picoline Oxidation to Nicotinic Acid on V-Ti-O Catalyst as Studied by in situ FTIR
Reaction Kinetics and Catalysis Letters. 2006. V.87. N2. P.387-394. DOI: 10.1007/s11144-006-0047-x WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Nov 25, 2005 |
| Accepted: | Dec 2, 2005 |
| Published print: | Apr 1, 2006 |
Identifiers:
| Web of science: | WOS:000236239300021 |
| Scopus: | 2-s2.0-33244497833 |
| Elibrary: | 13514840 |
| Chemical Abstracts: | 2006:169317 |
| Chemical Abstracts (print): | 145:230210 |
| OpenAlex: | W2329895362 |