Structure and Acid-Base Properties of Hexaaluminates Научная публикация
Журнал |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Вых. Данные | Год: 2008, Том: 93, Номер: 2, Страницы: 375-387 Страниц : 13 DOI: 10.1007/s11144-008-5300-z | ||
Ключевые слова | Acid-base properties, Hexaaluminate, XRD | ||
Авторы |
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Организации |
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Реферат:
Hexaaluminates SrAl12O19, BaAl12O19 and LaAl11O18 were prepared by co-precipitation of soluble nitrates of Sr, Ba, or La and Al using NH4HCO3 as a precipitating agent with subsequent calcination at 700–1400°C. The samples were characterized by adsorption methods, thermal analysis (TA and DTG), X-ray diffraction (XRD), and Fourier transform infrared (FTIR) spectroscopy of adsorbed probe molecules (CO and CDCl3). It was shown that calcination at 1200°C resulted in the formation of single-phase hexaaluminates in all the samples except for LaAl11O18, where an additional phase was found. The specific surface area of the samples was obtained in the range 16–22 m2/g. After the treatment at comparable conditions, the total concentrations of both surface Lewis acid sites and basic sites were found to increase in the series: BaAl12O19 < SrAl12O19 < LaAl11O18. However, the strongest basic sites were detected on the surface of BaAl12O19.
Библиографическая ссылка:
Bukhtiyarova M.V.
, Ivanova A.S.
, Plyasova L.M.
, Litvak G.S.
, Budneva A.A.
, Paukshtis E.A.
Structure and Acid-Base Properties of Hexaaluminates
Reaction Kinetics and Catalysis Letters. 2008. V.93. N2. P.375-387. DOI: 10.1007/s11144-008-5300-z WOS Scopus РИНЦ CAPlusCA OpenAlex
Structure and Acid-Base Properties of Hexaaluminates
Reaction Kinetics and Catalysis Letters. 2008. V.93. N2. P.375-387. DOI: 10.1007/s11144-008-5300-z WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: | 19 февр. 2008 г. |
Принята к публикации: | 21 февр. 2008 г. |
Опубликована в печати: | 1 апр. 2008 г. |
Опубликована online: | 27 нояб. 2008 г. |
Идентификаторы БД:
Web of science: | WOS:000255003000024 |
Scopus: | 2-s2.0-57249086443 |
РИНЦ: | 13581897 |
Chemical Abstracts: | 2008:561955 |
Chemical Abstracts (print): | 150:549003 |
OpenAlex: | W2039716260 |