Cu(II) and Cu(I) Complexes with 2-(3,5-Diphenyl-1H–pyrazole-1-yl)-4,6-diphenylpyrimidine: Synthesis and Structure. Catalytic Activity of Cu(II) Compounds in Reaction of Ethylene Polymerization | Sciact - CRIS-system of Boreskov Institute of Catalysis

Cu(II) and Cu(I) Complexes with 2-(3,5-Diphenyl-1H–pyrazole-1-yl)-4,6-diphenylpyrimidine: Synthesis and Structure. Catalytic Activity of Cu(II) Compounds in Reaction of Ethylene Polymerization Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 2006, Volume: 32, Number: 3, Pages: 199-207 Pages count : 9 DOI: 10.1134/S1070328406030067

Tags

Acetonitrile; Catalytic Activity; Nitrogen Atom; Pyrimidine; Halide

Authors

Bushuev M.B. ¹ , Krivopalov V.P. ² , Semikolenova N.V. ³ , Peresypkina E.V. ¹ , Virovets A.V. ¹ , Sheludyakova L.A. ¹ , Lavrenova L.G. ¹ , Zakharov V.A. ³ , Larionov S.V. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia
2	Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
3	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

The Cu(II) and Cu(I) complexes with 2-(3,5-diphenyl-1 H -pyrazole-1-yl)-4,6-diphenylpyrimidine (L) of the composition CuLX 2 (X = Cl, Br) and CuL(MeCN)Br are synthesized. According to X-ray diffraction data, the complexes have molecular structures. The molecules L are coordinated to the copper atom in bidentate-cyclic mode, i.e., through the N 2 atom of pyrazole and N 1 atom of pyrimidine rings. The coordination polyhedron of the Cu 2+ ion in CuLX 2 compounds is completed to a distorted tetrahedron with halide ions, that of the Cu + ion in CuL(MeCN)Br compounds, with the bromide ion and the nitrogen atom of acetonitrile molecule. The CuLX 2 complexes (X = Cl, Br) in combination with cocatalysts (methylaluminoxane and triisobutylaluminium) exhibit catalytic activity in ethylene polymerization.

Bushuev M.B. , Krivopalov V.P. , Semikolenova N.V. , Peresypkina E.V. , Virovets A.V. , Sheludyakova L.A. , Lavrenova L.G. , Zakharov V.A. , Larionov S.V.
Cu(II) and Cu(I) Complexes with 2-(3,5-Diphenyl-1H–pyrazole-1-yl)-4,6-diphenylpyrimidine: Synthesis and Structure. Catalytic Activity of Cu(II) Compounds in Reaction of Ethylene Polymerization
Russian Journal of Coordination Chemistry. 2006. V.32. N3. P.199-207. DOI: 10.1134/S1070328406030067 WOS Scopus РИНЦ ANCAN OpenAlex

Бушуев М.Б. , Кривопалов В.П. , Семиколенова Н.В. , Пересыпкина Е.В. , Вировец А.В. , Шелудякова Л.А. , Лавренова Л.Г. , Захаров В.А. , Ларионов С.В.
Синтез и структура координационных соединений меди(II) и меди(I) с 2-(3,5-дифенил-1 Н-пиразол-1 -ил)-4,6-дифенилпиримидином. Каталитическая активность соединений меди(II) в реакции полимеризации этилена
Координационная химия. 2006. Т.32. №3. С.208-216. RSCI РИНЦ

Submitted:	Jun 21, 2005
Published print:	Mar 1, 2006

Web of science:	WOS:000236491000006
Scopus:	2-s2.0-33645148488
Elibrary:	13514975
Chemical Abstracts:	2006:275018
Chemical Abstracts (print):	146:73896
OpenAlex:	W2007585124

DB	Citing
Web of science	14
Scopus	13
Elibrary	15
OpenAlex	18