A Study of Solid-State Rhodium(III) Sulfates | Sciact - CRIS-system of Boreskov Institute of Catalysis

A Study of Solid-State Rhodium(III) Sulfates Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 2008, Volume: 34, Number: 12, Pages: 917-923 Pages count : 7 DOI: 10.1134/S1070328408120087

Tags

Rhodium; Quadrupole Nucleus; Rhodium Atom; Polynuclear Species; Rhodium Sulfate

Authors

Shagabutdinova S.N. ¹ , Fedotov M.A. ² , Belyaev A.V. ¹ , Ilʹyashevich V.D. ³ , Pavlova E.I. ³

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090 Russia
2	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 5, Novosibirsk, 630090 Russia
3	OAO Krastsvetmet, Krasnoyarsk, Russia

Solid-state rhodium(III) sulfates and their aqueous solutions were examined by IR and electronic absorption spectroscopy, thermogravimetry, X-ray powder diffraction analysis, and 103Rh and 17O NMR spectroscopy. A study of the spontaneous aquation of freshly prepared solutions showed that this process results in an equilibrium between the subsystems of monomeric and oligomeric complexes. It was found that solid-state rhodium(III) sulfates vary in phase composition, basically consisting of dimeric and trimeric complexes.

Shagabutdinova S.N. , Fedotov M.A. , Belyaev A.V. , Ilʹyashevich V.D. , Pavlova E.I.
A Study of Solid-State Rhodium(III) Sulfates
Russian Journal of Coordination Chemistry. 2008. V.34. N12. P.917-923. DOI: 10.1134/S1070328408120087 WOS Scopus РИНЦ ANCAN OpenAlex

Шагабутдинова С.Н. , Федотов М.А. , Беляев А.В. , Ильяшевич В.Д. , Павлова Е.И.
Исследование твердых фаз сульфатов родия(III)
Координационная химия. 2008. Т.34. №12. С.930-936. РИНЦ

Submitted:	Nov 23, 2007
Published online:	Nov 28, 2008
Published print:	Dec 1, 2008

Web of science:	WOS:000261264000008
Scopus:	2-s2.0-57249105394
Elibrary:	13580068
Chemical Abstracts:	2008:1434403
Chemical Abstracts (print):	151:581120
OpenAlex:	W2020479455

DB	Citing
Web of science	3
Scopus	2
Elibrary	2
OpenAlex	4