Cu(II) Complexes with 4,6-Bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine, 4-(3,5-dimethyl-1H-pyrazole-1-yl)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine: Synthesis and Catalytic Activity in Ethylene Polymerization Reactionpolymerization Reaction | Sciact - CRIS-system of Boreskov Institute of Catalysis

Cu(II) Complexes with 4,6-Bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine, 4-(3,5-dimethyl-1H-pyrazole-1-yl)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine: Synthesis and Catalytic Activity in Ethylene Polymerization Reactionpolymerization Reaction Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 2007, Volume: 33, Number: 8, Pages: 601-606 Pages count : 6 DOI: 10.1134/S107032840708009X

Tags

Pyrimidine; Pyrazole; Coordination Chemistry; Hydrazine Hydrate; TIBA

Authors

Bushuev M.B. ¹ , Krivopalov V.P. ² , Semikolenova N.V. ³ , Shvedenkov Y.G. ¹ , Sheludyakova L.A. ¹ , Moskalenko G.G. ² , Lavrenova L.G. ¹ , Zakharov V.A. ³ , Larionov S.V. ¹

Affiliations

1	Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia
2	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
3	Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

The Cu(II) complexes with 4,6-bis(3,5-dimethyl-1 H -pyrazole-1-yl)pyrimidine (L 1 ) and 4-(3,5dimethyl 1 ç -pyrazole-1-yl)-6-(3,5-diphenyl 1 ç -pyrazole-1-yl)pyrimidine (L 2 ) of the composition Cu 2 L 1 Br 4 and Cu 2 L 2 A 4 (A = Cl, Br), respectively, were synthesized and studied by IR and magnetochemical methods. The molecular structure of the complexes is likely to be binuclear. In the presence of cocatalysts methylaluminoxane and triisobutylaluminium, the title complexes exhibit catalytic activity in the ethylene polymerization reaction.

Bushuev M.B. , Krivopalov V.P. , Semikolenova N.V. , Shvedenkov Y.G. , Sheludyakova L.A. , Moskalenko G.G. , Lavrenova L.G. , Zakharov V.A. , Larionov S.V.
Cu(II) Complexes with 4,6-Bis(3,5-dimethyl-1H-pyrazole-1-yl)pyrimidine, 4-(3,5-dimethyl-1H-pyrazole-1-yl)-6-(3,5-diphenyl-1H-pyrazole-1-yl)pyrimidine: Synthesis and Catalytic Activity in Ethylene Polymerization Reactionpolymerization Reaction
Russian Journal of Coordination Chemistry. 2007. V.33. N8. P.601-606. DOI: 10.1134/S107032840708009X WOS Scopus РИНЦ ANCAN OpenAlex

Бушуев М.Б. , Кривопалов В.П. , Семиколенова Н.В. , Шведенков Ю.Г. , Шелудякова Л.А. , Москаленко Г.Г. , Лавренова Л.Г. , Захаров В.А. , Ларионов С.В.
Синтез координационных соединений меди(II) c 4,6-бис(3,5-диметил-1Н-пиразол-1-ил)пиримидином, 4-(3,5-диметил-1Н-пиразол-1-ил)-6-(3,5-дифенил-1H-пиразол-1-ил)пиримидином и их каталитическая активность в реакции полимеризации этилена
Координационная химия. 2007. Т.33. №8. С.612-617. РИНЦ

Submitted:	Aug 9, 2006
Published print:	Aug 1, 2007

Web of science:	WOS:000249266700009
Scopus:	2-s2.0-34548444939
Elibrary:	13553209
Chemical Abstracts:	2007:985819
Chemical Abstracts (print):	149:523988
OpenAlex:	W2077149180

DB	Citing
Web of science	9
Scopus	9
Elibrary	7
OpenAlex	10