Active Surface Formation on a Promoted Copper Catalyst of the Partial Oxidation of Ethanol Full article
| Journal |
Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X |
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| Output data | Year: 2006, Volume: 80, Number: 5, Pages: 706-713 Pages count : 8 DOI: 10.1134/S0036024406050086 | ||||||
| Tags | Copper; Acetaldehyde; Phosphorus; Active Surface; Reaction Medium | ||||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | The Ministry of Education and Science of the Russian Federation | E02-5.0-340 |
| 2 | Council for Grants of the President of the Russian Federation | МД-243.2003.03 |
Abstract:
The catalytic properties, chemical composition, and morphology of the surface of electrolytic copper crystals promoted with phosphorus as catalysts of the partial oxidation of ethanol into acetaldehyde were studied. A mechanism of active copper surface formation under the action of the promoting admixture was suggested. Promotion was shown to cause the formation of copper polyphosphates on the surface. Particles of copper metal responsible for selective alcohol transformation are formed in a promoter layer under the action of the reaction medium.
Cite:
Magaeva A.A.
, Shmotin V.S.
, Vodyankina O.V.
, Knyazev A.S.
, Salanov A.N.
, Chesalov Y.A.
, Stoyanov E.S.
, Odegova G.V.
, Kurina L.N.
Active Surface Formation on a Promoted Copper Catalyst of the Partial Oxidation of Ethanol
Russian Journal of Physical Chemistry A. 2006. V.80. N5. P.706-713. DOI: 10.1134/S0036024406050086 WOS Scopus РИНЦ ANCAN OpenAlex
Active Surface Formation on a Promoted Copper Catalyst of the Partial Oxidation of Ethanol
Russian Journal of Physical Chemistry A. 2006. V.80. N5. P.706-713. DOI: 10.1134/S0036024406050086 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Магаева А.А.
, Шмотин В.С.
, Водянкина О.В.
, Князев А.С.
, Саланов А.Н.
, Чесалов Ю.А.
, Стоянов Е.С.
, Одегова Г.В.
, Курина Л.Н.
Формирование активной поверхности промотированного медного катализатора парциального окисления этанола
Журнал физической химии. 2006. Т.80. №5. С.818-825. RSCI РИНЦ
Формирование активной поверхности промотированного медного катализатора парциального окисления этанола
Журнал физической химии. 2006. Т.80. №5. С.818-825. RSCI РИНЦ
Dates:
| Submitted: | May 27, 2005 |
| Published print: | May 1, 2006 |
Identifiers:
| Web of science: | WOS:000245666000008 |
| Scopus: | 2-s2.0-33748972467 |
| Elibrary: | 13528648 |
| Chemical Abstracts: | 2006:406886 |
| Chemical Abstracts (print): | 146:208302 |
| OpenAlex: | W2048868976 |