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The Influence of Water on the Isomerization of α-Pinene in a Supercritical Aqueous–Alcoholic Solvent Научная публикация

Журнал Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X
Вых. Данные Год: 2008, Том: 82, Номер: 1, Страницы: 62-67 Страниц : 6 DOI: 10.1134/S0036024408010081
Ключевые слова Limonene; Ionic Product; Supercritical Water; Ionic Mechanism; Main Reaction Product;
Авторы Ermakova A.I. 1 , Chibiryaev A.M. 2,3 , Mikenin P.E. 1 , Sal’nikova O.I. 2 , Anikeev V.I. 1
Организации
1 Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, Novosibirsk, 630090 Russia
2 Vorozhtsov Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia
3 Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090 Russia

Информация о финансировании (2)

1 Российский фонд фундаментальных исследований 06-08-00024
2 Российский фонд фундаментальных исследований 05-08-65437

Реферат: The influence of water as a cosolvent and catalyst of the isomerization of α-pinene in a supercritical aqueous–alcoholic (ethanol) solvent was studied experimentally. At T = 657 K and p = 230 atm, an increase in the concentration of water in the reaction mixture was found to increase the rate of the reaction and its selectivity with respect to the desired product, limonene. Water exhibited the properties of an acid catalyst because of its ionization. Mathematical experimental data processing was performed to evaluate and separate the contributions of the radical and ionic paths to the total rate of the reactions that occurred during the thermal isomerization of α-pinene.
Библиографическая ссылка: Ermakova A.I. , Chibiryaev A.M. , Mikenin P.E. , Sal’nikova O.I. , Anikeev V.I.
The Influence of Water on the Isomerization of α-Pinene in a Supercritical Aqueous–Alcoholic Solvent
Russian Journal of Physical Chemistry A. 2008. V.82. N1. P.62-67. DOI: 10.1134/S0036024408010081 WOS Scopus РИНЦ CAPlusCA OpenAlex
Оригинальная: Ермакова А. , Чибиряев А.М. , Микенин П.Е. , Сальникова О.И. , Аникеев В.И.
Влияние воды на изомеризацию α-пинена в сверхкритическом водно-спиртовом растворителе
Журнал физической химии. 2008. Т.82. №1. С.71-76. РИНЦ
Даты:
Поступила в редакцию: 20 окт. 2006 г.
Опубликована в печати: 1 янв. 2008 г.
Идентификаторы БД:
Web of science: WOS:000253722500008
Scopus: 2-s2.0-38149086765
РИНЦ: 13571048
Chemical Abstracts: 2008:269198
Chemical Abstracts (print): 148:517154
OpenAlex: W2460508405
Цитирование в БД:
БД Цитирований
Web of science 5
Scopus 10
РИНЦ 9
OpenAlex 12
Альметрики: