The Special Features of Phase Equilibria in a-Pinene–Water Binary Mixtures in the Sub- and Supercritical States Full article
| Journal |
Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X |
||||||
|---|---|---|---|---|---|---|---|
| Output data | Year: 2008, Volume: 82, Number: 6, Pages: 928-932 Pages count : 5 DOI: 10.1134/S0036024408060101 | ||||||
| Tags | Limonene; Supercritical Condition; Critical Curve; Azeotropic Mixture; Dependent Pair | ||||||
| Authors |
|
||||||
| Affiliations |
|
Funding (2)
| 1 | Russian Foundation for Basic Research | 06-08-00024 |
| 2 | Russian Foundation for Basic Research | 05-08-65437 |
Abstract:
Phase equilibria in α-pinene–water binary mixtures under sub- and supercritical conditions were
studied by thermodynamic modeling. The compositions and boiling points of three-phase heteroazeotropic
mixtures were calculated as functions of pressure. The T and p regions of the existence of liquid–liquid and
vapor–liquid two-phase mixtures were determined. The Tcmix and pcmix critical curve coordinates depending on
mixture composition were found. The Tcmix curve exhibited an anomaly in the form of a minimum. The TAz−pAz
heteroazeotropic line ended at the minimum point of the critical curve.
Cite:
Ermakova A.I.
, Chibiryaev A.M.
, Kozhevnikov I.V.
, Mikenin P.E.
, Anikeev V.I.
The Special Features of Phase Equilibria in a-Pinene–Water Binary Mixtures in the Sub- and Supercritical States
Russian Journal of Physical Chemistry A. 2008. V.82. N6. P.928-932. DOI: 10.1134/S0036024408060101 WOS Scopus РИНЦ ANCAN OpenAlex
The Special Features of Phase Equilibria in a-Pinene–Water Binary Mixtures in the Sub- and Supercritical States
Russian Journal of Physical Chemistry A. 2008. V.82. N6. P.928-932. DOI: 10.1134/S0036024408060101 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Ермакова А.И.
, Чибиряев А.М.
, Кожевников И.В.
, Микенин П.Е.
, Аникеев В.И.
Особенности фазового равновесия бинарных смесей α-пинен-вода в до- и сверхкритическом состояниях
Журнал физической химии. 2008. Т.82. №6. С.1059-1063. РИНЦ
Особенности фазового равновесия бинарных смесей α-пинен-вода в до- и сверхкритическом состояниях
Журнал физической химии. 2008. Т.82. №6. С.1059-1063. РИНЦ
Dates:
| Submitted: | Feb 12, 2007 |
| Published print: | Jun 1, 2008 |
| Published online: | Jun 1, 2008 |
Identifiers:
| Web of science: | WOS:000257383400010 |
| Scopus: | 2-s2.0-44449178673 |
| Elibrary: | 13592816 |
| Chemical Abstracts: | 2008:678387 |
| Chemical Abstracts (print): | 149:209014 |
| OpenAlex: | W2062690717 |