The Effect of N-Heterocyclic Carbene Ligands in the Palladium-Catalyzed Cross-Coupling Reaction of K[C6F5BF3] with Aryl Iodides and Aryl Bromides | Sciact - CRIS-system of Boreskov Institute of Catalysis

The Effect of N-Heterocyclic Carbene Ligands in the Palladium-Catalyzed Cross-Coupling Reaction of K[C6F5BF3] with Aryl Iodides and Aryl Bromides Full article

Journal

Tetrahedron
ISSN: 0040-4020 , E-ISSN: 1464-5416

Output data

Year: 2008, Volume: 64, Number: 25, Pages: 5920-5924 Pages count : 5 DOI: 10.1016/j.tet.2008.04.043, 10.1002/chin.200843095

Tags

Cross-coupling, N-Heterocyclic carbene, Palladium, Polyfluoroorganoboron compounds, Polyfluorophenyltrifluoroborate salt

Authors

Adonin Nicolay Yu. ¹ , Babushkin Dmitrii E. ¹ , Parmon Valentin N. ¹ , Bardin Vadim V. ² , Kostin Gennadiy A. ³ , Mashukov Vasiliy I. ³ , Frohn Hermann-Josef ⁴

Affiliations

1	G.K. Boreskov Institute of Catalysis SB RAS, Lavrent’ev ave., 5, 630090 Novosibirsk, Russia
2	N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS, Lavrent’ev ave., 9, 630090 Novosibirsk, Russia
3	A.V. Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrent’ev ave., 3, 630090 Novosibirsk, Russia
4	Inorganic Chemistry, Duisburg-Essen University, Lotharstr., 1, 47048 Duisburg, Germany

The effect of N-heterocyclic carbene (NHC) ligands on the catalytic activity of in situ generated palladium complexes in the model cross-coupling reaction of K[C6F5BF3] with 4-FC6H4I was studied. Based on the obtained results, a series of pentafluorobiphenyls C6F5C6H4X were prepared from K[C6F5BF3] and XC6H4I or 4-CF3C6H4Br in high yields under aerobic conditions.

Adonin N.Y. , Babushkin D.E. , Parmon V.N. , Bardin V.V. , Kostin G.A. , Mashukov V.I. , Frohn H-J.
The Effect of N-Heterocyclic Carbene Ligands in the Palladium-Catalyzed Cross-Coupling Reaction of K[C6F5BF3] with Aryl Iodides and Aryl Bromides
Tetrahedron. 2008. V.64. N25. P.5920-5924. DOI: 10.1016/j.tet.2008.04.043, 10.1002/chin.200843095 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jan 17, 2008
Accepted:	Apr 10, 2008
Published online:	Apr 12, 2008
Published print:	Jun 16, 2008

Web of science:	WOS:000256559200011
Scopus:	2-s2.0-43449085777
Elibrary:	13577179
Chemical Abstracts:	2008:606172
Chemical Abstracts (print):	149:152806
OpenAlex:	W2003981586

DB	Citing
Web of science	38
Scopus	37
Elibrary	39
OpenAlex	40