Phenol Oxidation in Supercritical Water in a Well-Stirred Continuous Reactor Full article
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Theoretical Foundations of Chemical Engineering
ISSN: 0040-5795 , E-ISSN: 1608-3431 |
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| Output data | Year: 2006, Volume: 40, Number: 2, Pages: 168-174 Pages count : 7 DOI: 10.1134/S0040579506020096 | ||
| Tags | Phenol; Enthalpy; Heat Capacity; Thermodynamic Property; Total Pressure | ||
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Abstract:
A well-stirred reactor for phenol and acetic acid oxidation in supercritical water is considered. A mathematical model of an adiabatic reactor is formulated. A numerical algorithm for solving the model equations using the homotopy method is developed. The model takes into account specific features of processes under supercritical conditions, namely, the changes in the thermodynamic properties (enthalpy, heat capacity, and critical parameters) of mixtures with a change in pressure and temperature. The thermodynamic properties are calculated by methods of nonideal thermodynamics. It is shown that there is a multiplicity of steady-state solutions at various reactor performances. The results of numerical analysis of the effect of the inlet flow temperature, the amount of methanol (fuel) fed, and the total pressure on the reactor performance are presented.
Cite:
Yermakova A.
, Mikenin P.E.
, Anikeev V.I.
Phenol Oxidation in Supercritical Water in a Well-Stirred Continuous Reactor
Theoretical Foundations of Chemical Engineering. 2006. V.40. N2. P.168-174. DOI: 10.1134/S0040579506020096 WOS Scopus РИНЦ ANCAN OpenAlex
Phenol Oxidation in Supercritical Water in a Well-Stirred Continuous Reactor
Theoretical Foundations of Chemical Engineering. 2006. V.40. N2. P.168-174. DOI: 10.1134/S0040579506020096 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Ермакова А.
, Микенин П.Е.
, Аникеев В.И.
Окисление фенола в сверхкритической воде в проточном реакторе идеального смешения
Теоретические основы химической технологии. 2006. Т.40. №2. С.184-190. RSCI РИНЦ
Окисление фенола в сверхкритической воде в проточном реакторе идеального смешения
Теоретические основы химической технологии. 2006. Т.40. №2. С.184-190. RSCI РИНЦ
Dates:
| Submitted: | Apr 25, 2005 |
| Published print: | Mar 1, 2006 |
Identifiers:
| Web of science: | WOS:000237235800009 |
| Scopus: | 2-s2.0-33646189175 |
| Elibrary: | 13515109 |
| Chemical Abstracts: | 2006:373346 |
| Chemical Abstracts (print): | 146:186298 |
| OpenAlex: | W2063017290 |