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RDF Method Application to Phase Analysis of X-Ray Amorphous Products of Gibbsite Thermal Activation Full article

Conference 10th European Powder Diffraction Conference
01-04 Sep 2006 , Geneva
Journal Zeitschrift fur Kristallographie Supplement
ISSN: 0930-486X
Output data Year: 2007, Volume: 2, Number: 26, Pages: 279-282 Pages count : 4 DOI: 10.1524/9783486992540-044
Tags Alumina, Gibbsite thermal activation, Phase composition, Radial distribution function of electron density
Authors Shefer K.I. 1 , Moroz E.M. 1 , Isupova L.A. 1 , Kharina I.V. 1 , Tanashev Yu.Yu. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Pr. Lavrentieva 5, Novosibirsk, 630090, Russia

Abstract: The phase compositions of finely dispersed initial and rehydrated products of gibbsite thermal activation prepared by different technological methods - thermochemical activation (TCA) and centrifugal thermal activation (CTA) were studied using radial distribution function (RDF) method. The initial phase composition was shown to depend on the preparation method and determine the composition of the rehydrated products. Nuclei of different hydroxide phases are formed in addition to chi-alumina - pseudoboehmite in the case of the TCA process and bayerite for the CTA process. This leads to different phase compositions of rehydrated products. For TCA, pseudoboehmite is the primary rehydration product, whereas bayerite is formed for CTA.
Cite: Shefer K.I. , Moroz E.M. , Isupova L.A. , Kharina I.V. , Tanashev Y.Y.
RDF Method Application to Phase Analysis of X-Ray Amorphous Products of Gibbsite Thermal Activation
Zeitschrift fur Kristallographie Supplement. 2007. V.2. N26. P.279-282. DOI: 10.1524/9783486992540-044 WOS Scopus РИНЦ OpenAlex
Dates:
Published print: Dec 31, 2007
Identifiers:
Web of science: WOS:000253340900012
Scopus: 2-s2.0-54849439365
Elibrary: 15001270
OpenAlex: W4244489409
Citing:
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Web of science 1
Scopus 1
Elibrary 2
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