Synthesis of Pt/Zn(OH)2/Cd0.3Zn0.7S for the Photocatalytic Hydrogen Evolution from Aqueous Solutions of Organic and Inorganic Electron Donors Under Visible Light Full article
| Conference |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015 , Казань |
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| Journal |
Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028 |
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| Output data | Year: 2016, Volume: 59, Number: 15, Pages: 1297-1304 Pages count : 8 DOI: 10.1007/s11244-016-0656-1 | ||||||
| Tags | Ethanol, Na2S/Na2SO3, Photocatalytic hydrogen production, Pt/Cd1−xZnxS, Visible light | ||||||
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| Affiliations |
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Funding (2)
| 1 | Federal Agency for Scientific Organizations | V.44.2.11. |
| 2 | Russian Foundation for Basic Research | 15-33-20458 |
Abstract:
The work discusses the preparation of multiphase Zn(OH)2/Cd1−xZnxS and Pt/Zn(OH)2/Cd1−xZnxS photocatalysts sensitive to visible light. The synthesized photocatalysts were investigated by X-ray diffraction, X-ray photoelectron spectroscopy, and HRTEM techniques. Photocatalytic activity of synthesized samples was investigated in the hydrogen evolution from aqueous solutions of inorganic and organic electron donors, Na2S/Na2SO3 and ethanol, respectively, under the influence of visible light with λ = 450 nm. The photocatalytic hydrogen evolution over said multiphase photocatalysts occurs after some induction period needed for the photocatalyst self-activation. The highest apparent quantum efficiencies achieved at 450 nm for hydrogen evolution from Na2S/Na2SO3 (over 20 % Zn(OH)2/Cd0.3Zn0.7S) and ethanol (over 1 % Pt/10 % Zn(OH)2/Cd0.3Zn0.7S) aqueous solutions were 39 and 6.1 % respectively, appearing to be quite high values for the photocatalytic hydrogen evolution under visible light.
Cite:
Markovskaya D.V.
, Kozlova E.A.
, Cherepanova S.V.
, Saraev A.A.
, Gerasimov E.Y.
, Parmon V.N.
Synthesis of Pt/Zn(OH)2/Cd0.3Zn0.7S for the Photocatalytic Hydrogen Evolution from Aqueous Solutions of Organic and Inorganic Electron Donors Under Visible Light
Topics in Catalysis. 2016. V.59. N15. P.1297-1304. DOI: 10.1007/s11244-016-0656-1 WOS Scopus РИНЦ ANCAN OpenAlex
Synthesis of Pt/Zn(OH)2/Cd0.3Zn0.7S for the Photocatalytic Hydrogen Evolution from Aqueous Solutions of Organic and Inorganic Electron Donors Under Visible Light
Topics in Catalysis. 2016. V.59. N15. P.1297-1304. DOI: 10.1007/s11244-016-0656-1 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published online: | Jul 25, 2016 |
| Published print: | Sep 1, 2016 |
Identifiers:
| Web of science: | WOS:000382849100005 |
| Scopus: | 2-s2.0-84984905375 |
| Elibrary: | 27570465 |
| Chemical Abstracts: | 2016:1246933 |
| Chemical Abstracts (print): | 165:349447 |
| OpenAlex: | W2486486951 |