Specific Features of Polyol Synthesis of Silver Nanoparticles with the Use of Solid Carboxylates as Precursors Full article
| Journal |
Colloid Journal of the Russian Academy of Sciences: Kolloidnyi Zhurnal
ISSN: 1061-933X , E-ISSN: 1608-3067 |
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| Output data | Year: 2016, Volume: 78, Number: 4, Pages: 515-524 Pages count : 10 DOI: 10.1134/S1061933X16040189 | ||||
| Tags | Carboxylation; Ethylene; Ethylene glycol; Mass spectrometry; Metal nanoparticles; Nanoparticles; Organic solvents; Polyols; Salts; Synthesis (chemical); X ray diffraction | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 15-13-00113 |
Abstract:
Electron microscopy, Xray diffraction, and chromatography⎯mass spectrometry have been
employed to investigate the reduction of solid silver caprylate in ethylene glycol with the formation of silver
nanoparticles. The structural characteristics of silver nanoparticles have been studied as depending on the
conditions of their synthesis, including temperature, reduction time, and silver salt concentration. It has been
found that, in the studied range of parameters under the conditions, when solid silver caprylate is dispersed
in ethylene glycol, the characteristics of resulting nanoparticles are almost independent of the synthesis tem
perature. This peculiarity is related to the fact that the formation and growth of nanoparticles occur on the
surface of silver salt crystals and are accompanied by gradual dissolution thereof. In this system, ethylene gly
col plays the roles of a reductant and a solvent for liquid reaction products.
Cite:
Titkov A.I.
, Gerasimov E.Y.
, Shashkov M.V.
, Logutenko O.A.
, Bulina N.V.
, Yukhin Y.M.
, Lyakhov N.Z.
Specific Features of Polyol Synthesis of Silver Nanoparticles with the Use of Solid Carboxylates as Precursors
Colloid Journal of the Russian Academy of Sciences: Kolloidnyi Zhurnal. 2016. V.78. N4. P.515-524. DOI: 10.1134/S1061933X16040189 WOS Scopus РИНЦ AN OpenAlex
Specific Features of Polyol Synthesis of Silver Nanoparticles with the Use of Solid Carboxylates as Precursors
Colloid Journal of the Russian Academy of Sciences: Kolloidnyi Zhurnal. 2016. V.78. N4. P.515-524. DOI: 10.1134/S1061933X16040189 WOS Scopus РИНЦ AN OpenAlex
Original:
Титков А.И.
, Герасимов Е.Ю.
, Шашков М.В.
, Логутенко О.А.
, Булина Н.В.
, Юхин Ю.М.
, Ляхов Н.З.
Особенности полиольного синтеза наночастиц серебра с использованием твердых карбоксилатов в качестве прекурсоров
Коллоидный журнал. 2016. Т.78. №4. С.490-500. DOI: 10.7868/S0023291216040182 РИНЦ OpenAlex
Особенности полиольного синтеза наночастиц серебра с использованием твердых карбоксилатов в качестве прекурсоров
Коллоидный журнал. 2016. Т.78. №4. С.490-500. DOI: 10.7868/S0023291216040182 РИНЦ OpenAlex
Dates:
| Submitted: | Nov 30, 2015 |
| Published print: | Jul 1, 2016 |
| Published online: | Jul 20, 2016 |
Identifiers:
| Web of science: | WOS:000380227500013 |
| Scopus: | 2-s2.0-84978764808 |
| Elibrary: | 27076142 |
| Chemical Abstracts: | 2016:1192789 |
| OpenAlex: | W2494511726 |