Evolution of Active Ingredients and Catalytic Properties of Pt-Sn/Al2O3 Catalysts in the Selective Deoxygenation Reaction of Vegetable Oils | Sciact - CRIS-system of Boreskov Institute of Catalysis

Evolution of Active Ingredients and Catalytic Properties of Pt-Sn/Al2O3 Catalysts in the Selective Deoxygenation Reaction of Vegetable Oils Full article

Journal

Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532

Output data

Year: 2016, Volume: 56, Number: 7, Pages: 607-615 Pages count : 9 DOI: 10.1134/S0965544116070045

Tags

decarbonylation, decarboxylation, deoxygenation, heterometallic complexes, nano-sized clusters, rapeseed oil, triglycerides

Authors

Chistyakov A.V. ¹ , Kriventsov V.V. ² , Naumkin A.V. ³ , Pereyaslavtsev A.Yu. ⁴ , Zharova P.A. ¹ , Tsodikov M.V. ^1,4

Affiliations

1	Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991 Russia
2	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, pr. Lavrent’eva 5, Novosibirsk, 630090 Russia
3	Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991 Russia
4	Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul.Kosygina 4, Moscow, 119991 Russia

Funding (1)

Russian Science Foundation

15-13-30034

The evolution of the structure of Pt–Sn/Al2O3 catalysts and their catalytic properties in the reaction of the reductive deoxygenation of rapeseed oil fatty acid triglycerides (FATGs) have been studied. The catalysts were prepared by deposition from an organic solution of a mixture of platinum and tin compounds, as well as a heterometallic (PPh4)3[Pt(SnCl3)5] complex, in which platinum and tin atoms are linked by a metal–metal bond. It has been shown that the use of the heterometallic complex as a precursor with a tin to platinum molar ratio of 5 results in the formation of clusters of nanosized tin (2+; 4+) oxides and particles of a metastable PtSn3 ± δ alloy on the surface of the catalyst after reductive activation. In the presence of this catalyst, the exhaustive conversion of the feed FATGs and the selectivity for hydrocarbons above 98% have been achieved. The gaseous products CO, CO2, and CH4 are formed in trace quantities. The results show that the deoxygenation occurs not via the known decarboxylation and decarbonylation route, but also through the step of the selective reduction of oxygen and almost complete suppression of cracking of the organic moieties of FATGs.

Chistyakov A.V. , Kriventsov V.V. , Naumkin A.V. , Pereyaslavtsev A.Y. , Zharova P.A. , Tsodikov M.V.
Evolution of Active Ingredients and Catalytic Properties of Pt-Sn/Al2O3 Catalysts in the Selective Deoxygenation Reaction of Vegetable Oils
Petroleum Chemistry. 2016. V.56. N7. P.607-615. DOI: 10.1134/S0965544116070045 WOS Scopus РИНЦ AN OpenAlex

Чистяков А.В. , Кривенцов В.В. , Наумкин А.В. , Переяславцев А.Ю. , Жарова П.А. , Цодиков М.В.
Эволюция активных компонентов и каталитические свойства PtSn/Al2O3 -катализаторов в реакции селективной деоксигенации растительных масел
Нефтехимия. 2016. Т.56. №4. С.375-383. DOI: 10.7868/S0028242116040043 РИНЦ OpenAlex

Submitted:	Nov 16, 2015
Published print:	Jul 1, 2016
Published online:	Jul 31, 2016

Web of science:	WOS:000385149300009
Scopus:	2-s2.0-84981155173
Elibrary:	27123198
Chemical Abstracts:	2016:1277349
OpenAlex:	W2484904166

DB	Citing
Web of science	8
Scopus	8
Elibrary	8
OpenAlex	9