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EPR and DFT Study of the Ethylene Reaction with O− Radicals on the Surface of Nanocrystalline MgO Научная публикация

Журнал Research on Chemical Intermediates
ISSN: 0922-6168 , E-ISSN: 1568-5675
Вых. Данные Год: 2017, Том: 43, Номер: 2, Страницы: 1047-1061 Страниц : 15 DOI: 10.1007/s11164-016-2682-9
Ключевые слова DFT, EPR, Ethylene, MgO, O− radicals
Авторы Volodin Alexander M. 1 , Avdeev Vasilii I. 1 , Malykhin Sergei E. 1 , Bedilo Alexander F. 1,2
Организации
1 Boreskov Institute of Catalysis SB RAS, Prospekt Lavrentieva 5, Novosibirsk, Russia 630090
2 Novosibirsk Institute of Technology, Moscow State University of Design and Technology Branch, Krasny Prospekt 35, Novosibirsk, Russia 630099

Информация о финансировании (2)

1 Российский фонд фундаментальных исследований 15-03-08070
2 Российский фонд фундаментальных исследований 14-03-01110

Реферат: Different radical forms of oxygen (O−, O 2 − and O 3 − ) on the surface of nanocrystalline MgO are well known. It was earlier demonstrated that EPR-silent species with properties very similar to those of O− radicals exist on the surface of magnesium oxide in addition to the O− radicals observed by EPR. In this study we characterized the reactivity of these two types of O− radicals in reaction with ethylene. It was demonstrated that this reaction yields different products for observable and unobservable O− radicals. Conventional O−3CO3C− radicals generated by MgO illumination with UV light at room temperature in the presence of oxygen initiate hydrogen atom abstraction from ethylene to form secondary radicals H2C=C− with hyperfine splitting A 1 = 59 G, A 2 = 6 G. The O−4CO4C− radicals not observed directly by EPR were synthesized by MgO illumination in the presence of oxygen at 163 K followed by evacuation at 203 K. They were shown to react with ethylene to form an addition product with two groups of two equivalent protons with isotropic hyperfine constants A 1 = 38 G and A 2 = 23 G. Such radicals were obtained for the first time by reaction of O− radicals with ethylene on the MgO surface. Their concentration was approximately equal to the concentration of [O−4CO4C−·O2] complexes observed by EPR before the oxygen desorption. The structures of both radicals were simulated by DFT, and a good match between the experimental and computational results was obtained.
Библиографическая ссылка: Volodin A.M. , Avdeev V.I. , Malykhin S.E. , Bedilo A.F.
EPR and DFT Study of the Ethylene Reaction with O− Radicals on the Surface of Nanocrystalline MgO
Research on Chemical Intermediates. 2017. V.43. N2. P.1047-1061. DOI: 10.1007/s11164-016-2682-9 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 10 июн. 2016 г.
Принята к публикации: 19 июл. 2016 г.
Опубликована online: 12 авг. 2016 г.
Опубликована в печати: 1 февр. 2017 г.
Идентификаторы БД:
Web of science: WOS:000394374300031
Scopus: 2-s2.0-84982099151
РИНЦ: 29464983
Chemical Abstracts: 2016:1348878
Chemical Abstracts (print): 166:165526
OpenAlex: W2512109274
Цитирование в БД:
БД Цитирований
Web of science 7
Scopus 7
РИНЦ 7
OpenAlex 7
Альметрики: