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Dynamics of Water Vapour Adsorption by a Monolayer of Loose AQSOA™-FAM-Z02 Grains: Indication of Inseparably Coupled Heat and Mass Transfer Full article

Journal Energy
ISSN: 0360-5442 , E-ISSN: 1873-6785
Output data Year: 2016, Volume: 114, Pages: 767-773 Pages count : 7 DOI: 10.1016/j.energy.2016.08.056
Tags Adsorption chillers, Adsorption dynamics, Dynamic optimization, Heat & mass transfer, Specific cooling power
Authors Girnik Ilya S. 1,2 , Aristov Yuri I. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Pr. Lavrentieva 5, 630090, Novosibirsk, Russia
2 Novosibirsk State University, Pirogova st, 2, 630090, Novosibirsk, Russia

Funding (2)

1 Federal Agency for Scientific Organizations V.46.2.4.
2 Russian Foundation for Basic Research 14-08-01186

Abstract: Dynamics of water adsorption in an adsorption chiller (AC) determines the specific cooling power and the AC size. The dynamics, in its turn, strongly depends on the configuration of an “adsorbent – heat exchanger” (Ad-HEx). Here we considered the simplest, monolayer, configuration of the Ad-HEx and studied the water ad-/desorption dynamics as a function of the grain size (0.2–2.1 mm), temperature drop (16–36 °C), and pressure (7–47 mbar) for a commercial adsorbent AQSOA™-FAM-Z02. The dynamics was measured by a Volumetric Large Temperature Jump method under typical conditions of isobaric stages of real AC cycle. It is found that the initial part of all kinetic curves is exponential and can be described by a single characteristic time τ. This time depends on the grain size R as τ ∼ Rα, where the index α is constant over the whole range of the grain sizes, and its value is 1.33 and 1.20 for adsorption and desorption runs, respectively. The α-constancy may indicate an inseparable coupling of heat and mass transfer in the monolayer configuration of AQSOA™-FAM-Z02 adsorbent bed. For grains of about 2 mm size, quite acceptable initial power (>2 kW/kg) is obtained. Thus, the monolayer configurations may result in fast adsorption dynamics, reasonable specific power and compact AC units.
Cite: Girnik I.S. , Aristov Y.I.
Dynamics of Water Vapour Adsorption by a Monolayer of Loose AQSOA™-FAM-Z02 Grains: Indication of Inseparably Coupled Heat and Mass Transfer
Energy. 2016. V.114. P.767-773. DOI: 10.1016/j.energy.2016.08.056 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Nov 6, 2015
Accepted: Aug 16, 2016
Published online: Aug 25, 2016
Published print: Nov 1, 2016
Identifiers:
Web of science: WOS:000387194800060
Scopus: 2-s2.0-84983548882
Elibrary: 27140545
Chemical Abstracts: 2016:1410462
Chemical Abstracts (print): 172:283929
OpenAlex: W2509641276
Citing:
DB Citing
Web of science 25
Scopus 25
Elibrary 23
OpenAlex 25
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