The Effect of Heat-Treatment Temperature of Cobalt–Boron Catalysts on Their Activity in Sodium Borohydride Hydrolysis Full article
| Conference |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015 , Казань |
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| Journal |
Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028 |
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| Output data | Year: 2016, Volume: 59, Number: 15, Pages: 1431-1437 Pages count : 7 DOI: 10.1007/s11244-016-0664-1 | ||||
| Tags | Catalyst, Cobalt, Hydrolysis, Reduction, Sodium borohydride, Solution | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 14-22-01045 |
Abstract:
The activity of cobalt–boron catalysts in sodium borohydride hydrolysis has been correlated with change of
structure in the active component of the catalysts upon their thermal treatment. It was shown that at temperatures to 300 C there takes place loss of water and hydrogen from the catalysts without noticeable changes in activity. At temperatures above 300 C the amorphous cobalt boride particles undergo crystallization to produce metallic cobalt with a hexagonal structure and this is seemingly the cause of the substantial fall in the rate of hydrogen generation in the presence of cobalt–boron catalysts.
Cite:
Netskina O.V.
, Ozerova A.M.
, Komova O.V.
, Kochubey D.I.
, Kanazhevskiy V.V.
, Ishchenko A.V.
, Simagina V.I.
The Effect of Heat-Treatment Temperature of Cobalt–Boron Catalysts on Their Activity in Sodium Borohydride Hydrolysis
Topics in Catalysis. 2016. V.59. N15. P.1431-1437. DOI: 10.1007/s11244-016-0664-1 WOS Scopus РИНЦ ANCAN OpenAlex
The Effect of Heat-Treatment Temperature of Cobalt–Boron Catalysts on Their Activity in Sodium Borohydride Hydrolysis
Topics in Catalysis. 2016. V.59. N15. P.1431-1437. DOI: 10.1007/s11244-016-0664-1 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published online: | Jul 20, 2016 |
| Published print: | Sep 1, 2016 |
Identifiers:
| Web of science: | WOS:000382849100017 |
| Scopus: | 2-s2.0-84984923152 |
| Elibrary: | 27024444 |
| Chemical Abstracts: | 2016:1215765 |
| Chemical Abstracts (print): | 165:369024 |
| OpenAlex: | W2491682029 |