Synthesis of Polystyrene Beads for Hard-Templating of Three-Dimensionally Ordered Macroporosity and Hierarchical Texture of Adsorbents and Catalysts Full article
| Conference |
EuropaCat-XII: 12th European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” 30 Aug - 4 Sep 2015 , Казань |
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| Journal |
Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028 |
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| Output data | Year: 2017, Volume: 60, Number: 1-2, Pages: 178-189 Pages count : 12 DOI: 10.1007/s11244-016-0719-3 | ||||
| Tags | 3DOM oxides, Alumina, Hierarchical zeolite, Polystyrene beads, Silica, Titania | ||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Russian Science Foundation | 14-13-01155 |
Abstract:
Methods of polystyrene beads producing with properties appropriate for catalyst and adsorbent synthesis have been investigated. Hierarchical silicalite-1 and Fe-silicalite-1 with zeolitic MFI structure, as well as three-dimensionally ordered titania, silica, alumina and zirconia have been prepared by hard-templating method using polystyrene beads. The materials were characterized by X-ray diffraction, scanning and transmission electron microscopies, low-temperature nitrogen adsorption technique and mercury porosimetry. Developed meso- and macroporous structure of the templated materials facilitated the supply of macromolecular reactants to the material surface and reduced the negative effect of byproduct deposition, resulting in favored advantages of the materials in a wide range of processes: hydroconversion of heavy oil, wet hydrogen peroxide oxidation of organic substrates in water, photocatalysis and chromatographic analysis. The obtained results of the material applications showed their potential attractiveness as catalysts and adsorbents.
Cite:
Parkhomchuk E.V.
, Semeykina V.S.
, Sashkina K.A.
, Okunev A.G.
, Lysikov A.I.
, Parmon V.N.
Synthesis of Polystyrene Beads for Hard-Templating of Three-Dimensionally Ordered Macroporosity and Hierarchical Texture of Adsorbents and Catalysts
Topics in Catalysis. 2017. V.60. N1-2. P.178-189. DOI: 10.1007/s11244-016-0719-3 WOS Scopus РИНЦ ANCAN OpenAlex
Synthesis of Polystyrene Beads for Hard-Templating of Three-Dimensionally Ordered Macroporosity and Hierarchical Texture of Adsorbents and Catalysts
Topics in Catalysis. 2017. V.60. N1-2. P.178-189. DOI: 10.1007/s11244-016-0719-3 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published online: | Sep 26, 2016 |
| Published print: | Feb 1, 2017 |
Identifiers:
| Web of science: | WOS:000395015100016 |
| Scopus: | 2-s2.0-85013928016 |
| Elibrary: | 29494588 |
| Chemical Abstracts: | 2016:1577815 |
| Chemical Abstracts (print): | 166:239793 |
| OpenAlex: | W2524745727 |