Promoting Effect of Ionic Liquids in Liquid-Phase Oxidation of Cyclohexane with a Mixture of О2 and Н2 Научная публикация
| Журнал |
Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905 |
||||
|---|---|---|---|---|---|
| Вых. Данные | Год: 2017, Том: 88, Страницы: 50-52 Страниц : 3 DOI: 10.1016/j.catcom.2016.09.020 | ||||
| Ключевые слова | Cyclohexane oxidation, Hydrogen, Ionic liquid, Molybdophosphoric acid, Oxygen, Pt catalyst | ||||
| Авторы |
|
||||
| Организации |
|
Информация о финансировании (1)
| 1 | Федеральное агентство научных организаций России | V.44.1.15. |
Реферат:
The low efficiency of H2 usage in the oxidation of organics with O2–H2 gas mixture is still a challenging problem. Here, a significant improvement of cyclohexane oxidation has been achieved by introduction of some ionic liquids into Pt/C–H3PMo12O40–CH3CN catalytic system. Even small amounts of BMImBr, Bu4NBr or Bu4NHSO4 inhibited H2O formation, enhanced efficiency of H2 consumption from 2 to 18–25%, and provided extraordinary high selectivity (92–98%) for the conversion of cyclohexane to cyclohexanol. The positive effect of the ionic liquids was explained by stabilization of an active peroxide species and inhibition of secondary oxidation of cyclohexanol.
Библиографическая ссылка:
Kuznetsova L.I.
, Kuznetsova N.I.
, Koscheeva O.S.
Promoting Effect of Ionic Liquids in Liquid-Phase Oxidation of Cyclohexane with a Mixture of О2 and Н2
Catalysis Communications. 2017. V.88. P.50-52. DOI: 10.1016/j.catcom.2016.09.020 WOS Scopus РИНЦ CAPlusCA OpenAlex
Promoting Effect of Ionic Liquids in Liquid-Phase Oxidation of Cyclohexane with a Mixture of О2 and Н2
Catalysis Communications. 2017. V.88. P.50-52. DOI: 10.1016/j.catcom.2016.09.020 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Поступила в редакцию: | 14 июн. 2016 г. |
| Принята к публикации: | 15 сент. 2016 г. |
| Опубликована online: | 16 сент. 2016 г. |
| Опубликована в печати: | 1 янв. 2017 г. |
Идентификаторы БД:
| Web of science: | WOS:000389117500012 |
| Scopus: | 2-s2.0-84988606166 |
| РИНЦ: | 28242138 |
| Chemical Abstracts: | 2016:1585053 |
| Chemical Abstracts (print): | 165:453333 |
| OpenAlex: | W2519890846 |