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Effect of Titanium–Magnesium Catalyst Morphology on the Properties of Polypropylene upon Propylene Polymerization in a Liquid Monomer Full article

Journal Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Output data Year: 2016, Volume: 8, Number: 3, Pages: 213-216 Pages count : 4 DOI: 10.1134/S2070050416030107
Tags polymerization, polypropylene properties, propylene, titanium-magnesium catalyst, Ziegler–Natta catalyst
Authors Salakhov I.I. 1 , Batyrshin A.Z. 1 , Sergeev S.A. 2 , Bukatov G.D. 2 , Barabanov A.A. 2 , Mats'ko M.A. 2 , Sakhabutdinov A.G. 1 , Zakharov V.A. 2
Affiliations
1 PAO Nizhnekamskneftekhim, Nizhnekamsk, 423574 Russia
2 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Abstract: The effect of the particle size of an IK-8-21 domestic titanium-magnesium catalyst on the properties of polypropylene (PP) produced during the polymerization of propylene in a liquid monomer is studied. Catalysts with particle sizes of 20 to 64 μm are shown to have high activity and identical sensitivity to hydrogen and allow PP to be obtained with a narrow distribution of particles over size, high isotacticity, and close values of crystallinity, melting temperature, and physicomechanical properties. A slight decrease in the activity and bulk density of PP powder is observed when the average size of catalyst particles is increased from 20 to 43 μm. A more notable reduction in the activity and bulk density of PP powder is observed for catalyst with particle sizes of 62 to 64 μm. IK-8-21 catalyst is not inferior to its foreign analogues with respect to the properties of the resulting PP
Cite: Salakhov I.I. , Batyrshin A.Z. , Sergeev S.A. , Bukatov G.D. , Barabanov A.A. , Mats'ko M.A. , Sakhabutdinov A.G. , Zakharov V.A.
Effect of Titanium–Magnesium Catalyst Morphology on the Properties of Polypropylene upon Propylene Polymerization in a Liquid Monomer
Catalysis in Industry. 2016. V.8. N3. P.213-216. DOI: 10.1134/S2070050416030107 WOS Scopus РИНЦ OpenAlex
Original: Салахов И.И. , Батыршин А.З. , Сергеев С.А. , Букатов Г.Д. , Барабанов А.А. , Мацько М.А. , Сахабутдинов А.Г. , Захаров В.А.
Влияние морфологии титан-магниевого катализатора в процессе полимеризации пропилена в среде жидкого мономера на свойства полипропилена.
Катализ в промышленности. 2016. №2. С.30-33. DOI: 10.18412/1816-0387-2016-2-30-33 РИНЦ AN OpenAlex
Dates:
Submitted: Jan 26, 2016
Published print: Jul 1, 2016
Published online: Oct 2, 2016
Identifiers:
Web of science: WOS:000388336000003
Scopus: 2-s2.0-84989339195
Elibrary: 27570941
OpenAlex: W2526770524
Citing:
DB Citing
Web of science 4
Scopus 5
Elibrary 4
OpenAlex 4
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