Stereoisomeric Pt(IV) Complexes with Threonine Full article
| Journal |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
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| Output data | Year: 2012, Volume: 38, Number: 5, Pages: 363-372 Pages count : 10 DOI: 10.1134/S1070328412040069 | ||||||
| Tags | Threonine; Coordination Chemistry; Bidentate Coordination; Monodentate Coordination; Complex Trans | ||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | The Ministry of Education and Science of the Russian Federation | 02.740.11.0628 |
Abstract:
Stereoisomeric Pt(IV) complexes with threonine (ThrH = HOCH(CH3)CH(NH2)COOH,
α-amino-β-hydroxybutyric acid) were obtained. In the complexes trans[Pt(SThrH)2Cl4] and
trans[Pt(RThrH)(SThrH)Cl4], the ThrH molecules act as monodentate ligands coordinated through the NH2 group. In the complexes cis and trans[Pt(SThr)2Cl2] and trans[Pt(RThr)(SThr)Cl2], the deprotonated ligands are coordinated in a bidentate fashion through the NH2 and COO–groups (R,S is the absolute configuration of the asymmetric carbon atom). All the complexes were identified using elemental analysis, IR spectroscopy, and 195Pt, 13C, and 1H NMR spectroscopy. The complexes trans[Pt(SThrH)2Cl4] · 3H2O and cis[Pt(SThr)2Cl2] · 2H2O were additionally characterized by X-ray diffraction.
Cite:
Krylova L.F.
, Kovtunova L.M.
, Romanenko G.V.
, Sheludyakova L.A.
Stereoisomeric Pt(IV) Complexes with Threonine
Russian Journal of Coordination Chemistry. 2012. V.38. N5. P.363-372. DOI: 10.1134/S1070328412040069 WOS Scopus РИНЦ ANCAN OpenAlex
Stereoisomeric Pt(IV) Complexes with Threonine
Russian Journal of Coordination Chemistry. 2012. V.38. N5. P.363-372. DOI: 10.1134/S1070328412040069 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Крылова Л.Ф.
, Ковтунова Л.М.
, Романенко Г.В.
, Шелудякова Л.А.
Стереоизомерные комплексы Pt(IV) с треонином
Координационная химия. 2012. Т.38. №5. С.377-386. РИНЦ
Стереоизомерные комплексы Pt(IV) с треонином
Координационная химия. 2012. Т.38. №5. С.377-386. РИНЦ
Dates:
| Submitted: | Mar 10, 2011 |
| Published print: | May 1, 2012 |
| Published online: | May 14, 2012 |
Identifiers:
| Web of science: | WOS:000304117400010 |
| Scopus: | 2-s2.0-84861406134 |
| Elibrary: | 17986209 |
| Chemical Abstracts: | 2012:686447 |
| Chemical Abstracts (print): | 157:62753 |
| OpenAlex: | W1989150716 |