Ethanol Dehydrogenation over Ag-CeO2/SiO2 Catalyst: Role of Ag-CeO2 Interface Full article
Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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Output data | Year: 2016, Volume: 528, Pages: 161-167 Pages count : 7 DOI: 10.1016/j.apcata.2016.10.005 | ||||||
Tags | Ag-CeO2 interface, Ag/SiO2, CeO2 additive, Ethanol dehydrogenation | ||||||
Authors |
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Affiliations |
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Funding (2)
1 | National Research Tomsk State University | 8.2.07.2015 |
2 | Russian Foundation for Basic Research | 14-33-50479 |
Abstract:
Small silver nanoparticles (less than 7 nm) supported on silica as well as silica modified with CeO2 were prepared by impregnation techniques, characterized by physical-chemical methods, and tested in dehydrogenation of ethanol into acetaldehyde. The addition of CeO2 was shown to increase the catalytic activity of the Ag/SiO2 catalyst. The close interaction of the CeO2 nanoparticles (3–5 nm) with supported silver nanoparticles increased the activity of the Ag/CeO2/SiO2 catalyst in both dehydrogenation and oxidative dehydrogenation of ethanol into acetaldehyde due to participation of the Ag-CeO2 interface in the ethanol activation or/and the spillover of active oxygen.
Cite:
Mamontov G.V.
, Grabchenko M.V.
, Sobolev V.I.
, Zaikovskii V.I.
, Vodyankina O.V.
Ethanol Dehydrogenation over Ag-CeO2/SiO2 Catalyst: Role of Ag-CeO2 Interface
Applied Catalysis A: General. 2016. V.528. P.161-167. DOI: 10.1016/j.apcata.2016.10.005 WOS Scopus РИНЦ ANCAN OpenAlex
Ethanol Dehydrogenation over Ag-CeO2/SiO2 Catalyst: Role of Ag-CeO2 Interface
Applied Catalysis A: General. 2016. V.528. P.161-167. DOI: 10.1016/j.apcata.2016.10.005 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: | Jun 9, 2016 |
Accepted: | Oct 6, 2016 |
Published online: | Oct 7, 2016 |
Published print: | Nov 25, 2016 |
Identifiers:
Web of science: | WOS:000388153300018 |
Scopus: | 2-s2.0-84994173192 |
Elibrary: | 27581891 |
Chemical Abstracts: | 2016:1694441 |
Chemical Abstracts (print): | 165:551066 |
OpenAlex: | W2531057053 |