Effect of Chromium Content on the Properties of a Alumina-Chromia Catalyst in Tetrachloroethylene Hydrofluorination | Sciact - CRIS-system of Boreskov Institute of Catalysis

Effect of Chromium Content on the Properties of a Alumina-Chromia Catalyst in Tetrachloroethylene Hydrofluorination Full article

Conference

13th International Conference of Students and Young Scientists - Prospects of Fundamental Sciences Development
26-29 Apr 2016 , Томск

Source

Prospects of Fundamental Sciences Development (PFSD-2016): Proceedings of the XIII International Conference of Students and Young Scientists
Compilation, 2016. ISBN 978-0-7354-1430-3.

Journal

AIP Conference Proceedings
ISSN: 0094-243X , E-ISSN: 1551-7616

Output data

Year: 2016, Volume: 1772, Article number : 030009, Pages count : 5 DOI: 10.1063/1.4964547

Authors

Petrov Roman ¹ , Zirka Alexander ¹ , Reshetnikov Sergey ¹

Affiliations

1	Boreskov institute of catalysis SB RAS, 5 Аkademica Lavrentieva str., Novosibirsk 630090 Russian Federation

Funding (1)

Russian Foundation for Basic Research

15-08-04789

The effect of chromium content on Cr2O3/Al2O3 catalyst activity of tetrachloroethylene hydrofluorination to pentafluoroethane (Freon R-125) is studied. Catalysts containing 15-95 wt % chromium oxide (on Cr2O3 basis) were prepared by the addition of a mixture of CrCl3 and AlCl3 solutions to a solution of ammonia. It is shown that catalytic activity linearly depends on the chromium content of the catalyst. A hydrofluorination scheme including main product and by-products formation routes is deduced from the observed dependences of particular products selectivity.

Petrov R. , Zirka A. , Reshetnikov S.
Effect of Chromium Content on the Properties of a Alumina-Chromia Catalyst in Tetrachloroethylene Hydrofluorination
In compilation Prospects of Fundamental Sciences Development (PFSD-2016): Proceedings of the XIII International Conference of Students and Young Scientists. 2016. – ISBN 978-0-7354-1430-3. DOI: 10.1063/1.4964547 WOS Scopus РИНЦ AN OpenAlex

Full text from publisher

Web of science:	WOS:000392692300025
Scopus:	2-s2.0-84994165286
Elibrary:	27583830
Chemical Abstracts:	2016:1765725
OpenAlex:	W2534799328

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