Catalytic Conversion of 1,2-dichloroethane over Ni-Pd System into Filamentous Carbon Material | Sciact - CRIS-system of Boreskov Institute of Catalysis

Catalytic Conversion of 1,2-dichloroethane over Ni-Pd System into Filamentous Carbon Material Full article

Conference

International Symposium on Catalytic Conversion of Energy and Resources
30 Jun - 2 Jul 2016 , Seoul

Journal

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Output data

Year: 2017, Volume: 293–294, Pages: 23-32 Pages count : 10 DOI: 10.1016/j.cattod.2016.11.020

Tags

1,2-dichloroethane, Carbon nanomaterial, Catalytic decomposition, Metal dusting, Ni-Pd alloy, Segmented filaments

Authors

Bauman Yurii I. ¹ , Shorstkaya Yuliya V. ² , Mishakov Ilya V. ^1,4 , Plyusnin Pavel E. ^2,3 , Shubin Yury V. ^2,3 , Korneev Denis V. ⁵ , Stoyanovskii Vladimir O. ¹ , Vedyagin Aleksey A. ^1,4

Affiliations

1	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 5, 630090, Novosibirsk, Russia
2	Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, 630090, Novosibirsk, Russia
3	Novosibirsk State University, ul. Pirogova 2, 630090, Novosibirsk, Russia
4	National Research Tomsk Polytechnic University, Tomsk, Lenin Avenue 30, 634050, Russia
5	State Research Center of Virology and Biotechnology “Vector”, 630559, Koltsovo, Russia

Funding (1)

Russian Foundation for Basic Research

16-33-60074

The alloyed Ni-Pd system with Pd content of 3 wt.% was prepared by coprecipitation method followed by reduction in hydrogen atmosphere at 800 °C. The formation of single-phase solid solution with unit cell parameter a = 3.532(1) Å (determined by (331) reflex at 2θ ≈ 145°) corresponding to NiPd alloy with weight ratio 97:3 was confirmed by XRD analysis. Kinetic studies on catalytic conversion of 1,2-dichloroethane (DCE) over NiPd alloy into carbon nanomaterial (CNM) were performed in a flow reactor equipped with McBain balances in a temperature range of 580–700 °C. It was shown that interaction of DCE with NiPd system results in a fast disintegration of pristine alloy with formation of submicron (0.2-0.9 μm) particles, which efficiently catalyze the growth of segmented carbon filaments. According to Raman spectroscopy and transmission electron microscopy data, hydrogen concentration in reaction mixture strongly affects the structural features and density of segmented filaments. The average values of inter-segmental distance calculated from TEM micrographs of carbon filaments were found to be 96, 46, 16 nm for hydrogen concentration of 23, 36 and 47 vol.%, respectively. Strongly chemisorbed chlorine species were suggested to be responsible for the cyclic perturbations in carbon transfer and deposition. Obtained carbon nanomaterials were characterized with comparatively high specific surface area (300–400 m2/g) and extremely low bulk density (< 0.03 g/ml).

Bauman Y.I. , Shorstkaya Y.V. , Mishakov I.V. , Plyusnin P.E. , Shubin Y.V. , Korneev D.V. , Stoyanovskii V.O. , Vedyagin A.A.
Catalytic Conversion of 1,2-dichloroethane over Ni-Pd System into Filamentous Carbon Material
Catalysis Today. 2017. V.293–294. P.23-32. DOI: 10.1016/j.cattod.2016.11.020 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Aug 17, 2016
Accepted:	Nov 6, 2016
Published online:	Nov 14, 2016
Published print:	Sep 1, 2017

Web of science:	WOS:000405047100005
Scopus:	2-s2.0-85006817520
Elibrary:	31037996
Chemical Abstracts:	2016:1883379
Chemical Abstracts (print):	167:39144
OpenAlex:	W2549451406

DB	Citing
Web of science	29
Scopus	37
Elibrary	37
OpenAlex	35