Catalytic Oxidation of α-alkenes with Hydrogen Peroxide to Carboxylic Acids in the Presence of Peroxopolyoxotungstate Complexes Full article
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Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905 |
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| Output data | Year: 2017, Volume: 88, Pages: 45-49 Pages count : 5 DOI: 10.1016/j.catcom.2016.09.019 | ||
| Tags | Alpha-alkenes, Carboxylic acids, Peroxotungstate complexes, Phase-transfer catalysis, Quaternary ammonium cations | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Federal Agency for Scientific Organizations | V.44.2.8. |
| 2 | Russian Foundation for Basic Research | 16-03-00127 |
Abstract:
Fine organic synthesis investigation has been performed, focusing on the possibility of efficient oxidation of α-alkenes by hydrogen peroxide under conditions of phase transfer catalysis using bifunctional metal complex catalysts based on peroxotungsten compounds of general formula Q3{PO4[WO(O2)2]4}, where Q is organic cation containing quaternary nitrogen atom.
Catalysts screening has been done at oxidation of octene-1, decene-1 and dodecene-1 by 30% aqueous hydrogen peroxide to obtain carboxylic acids: heptanoic, nonanoic and undecanoic acids being of importance since used as precursors in the synthesis of various organic and biologically active compounds. This approach to the synthesis of carboxylic acids may be of interest for the processes of “green chemistry” occurring under mild conditions (Т < 100 °С, Р – atm) in one stage without organic solvents, and providing high target product yields (86–97%).
Cite:
Pai Z.P.
, Selivanova N.V.
, Oleneva P.V.
, Berdnikova P.V.
, Beskopyl'nyi A.M.
Catalytic Oxidation of α-alkenes with Hydrogen Peroxide to Carboxylic Acids in the Presence of Peroxopolyoxotungstate Complexes
Catalysis Communications. 2017. V.88. P.45-49. DOI: 10.1016/j.catcom.2016.09.019 WOS Scopus РИНЦ ANCAN OpenAlex
Catalytic Oxidation of α-alkenes with Hydrogen Peroxide to Carboxylic Acids in the Presence of Peroxopolyoxotungstate Complexes
Catalysis Communications. 2017. V.88. P.45-49. DOI: 10.1016/j.catcom.2016.09.019 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Jul 20, 2016 |
| Accepted: | Sep 14, 2016 |
| Published online: | Sep 15, 2016 |
| Published print: | Jan 1, 2017 |
Identifiers:
| Web of science: | WOS:000389117500011 |
| Scopus: | 2-s2.0-84988662371 |
| Elibrary: | 28273158 |
| Chemical Abstracts: | 2016:1585060 |
| Chemical Abstracts (print): | 165:487395 |
| OpenAlex: | W2518756491 |