Isostructural Metal-Carboxylates MIL-100(M) and MIL-53(M) (M: V, Al, Fe and Cr) as Catalysts for Condensation of Glycerol with Acetone | Sciact - CRIS-system of Boreskov Institute of Catalysis

Isostructural Metal-Carboxylates MIL-100(M) and MIL-53(M) (M: V, Al, Fe and Cr) as Catalysts for Condensation of Glycerol with Acetone Full article

Journal

Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875

Output data

Year: 2017, Volume: 529, Pages: 167-174 Pages count : 8 DOI: 10.1016/j.apcata.2016.11.006

Tags

Acetone, Glycerol, Metal-organic frameworks, MIL-100, MIL-53, Solketal

Authors

Timofeeva Maria N. ^1,3 , Panchenko Valentina N. ^1,4 , Khan Nazmul Abedin ² , Hasan Zubair ² , Prosvirin Igor P. ¹ , Tsybulya Sergey V. ¹ , Jhung Sung Hwa ²

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Prospekt Akad, Lavrentieva 5, 630090, Novosibirsk, Russian Federation
2	Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Sankyuck-Dong, Buk-Ku, Daegu 702-701, Republic of Korea
3	Novosibirsk State Technichal University, Prospekt K. Marksa 20, 630092, Novosibirsk, Russian Federation
4	Novosibirsk State University, st. Pirogova 2, 630090, Novosibirsk, Russian Federation

Funding (2)

1	Federal Agency for Scientific Organizations	V.44.2.12.
2	Ministry of Science ICT and Future Planning	2015R1A2A1A15055291

The synthesis of solketal from acetone and glycerol (I) was investigated in the presence of the isostructural MOFs of the families MIL-100(M) and MIL-53(M) (M = V, Al, Fe and Cr) and mixed MIL-53(Al,V) (Al/V– 100/0, 75/25, 50/50, 25/75 and 0/100 atom/atom). The main products were a five-membered solketal (2,2-dimethyl-1,3-dioxane-4-methanol, (II)) and a six-membered acetal (2,2-dimethyl-dioxane-5-ol, (III)). It was demonstrated that the reaction rate and isomer selectivity depend on different parameters such as the type of metal ion, the length of the M-O bond, the rate constant for the exchange of the water molecules from the first coordination sphere of a metal ion and the value of the zero point of the surface charge (pHPZC). Investigation of mixed MIL-53(Al,V) shows that the reaction rate and selectivity towards (II) increase with increasing V3+ content in MIL-53(Al,V). V-containing MOFs possess a high activity and selectivity at 25 ◦C. The efficiencies of MIL-100(V) and MIL-47(V) were higher than those of H2SO4, SnCl2 and p-toluenesulfonic acid at 25 ◦C. The MIL-100(V) catalyst showed good reusability for 4 catalyst recycles.

Timofeeva M.N. , Panchenko V.N. , Khan N.A. , Hasan Z. , Prosvirin I.P. , Tsybulya S.V. , Jhung S.H.
Isostructural Metal-Carboxylates MIL-100(M) and MIL-53(M) (M: V, Al, Fe and Cr) as Catalysts for Condensation of Glycerol with Acetone
Applied Catalysis A: General. 2017. V.529. P.167-174. DOI: 10.1016/j.apcata.2016.11.006 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jul 11, 2016
Accepted:	Nov 7, 2016
Published online:	Nov 7, 2016
Published print:	Jan 1, 2017

Web of science:	WOS:000390084200018
Scopus:	2-s2.0-84995577366
Elibrary:	28260820
Chemical Abstracts:	2016:1869636
Chemical Abstracts (print):	166:343267
OpenAlex:	W2549567320

DB	Citing
Web of science	69
Scopus	75
Elibrary	68
OpenAlex	73