A Study of Complex Phosphovanadomolybdates [PVxMo12−xO40]−(3+x) by Reversed-Phase HPLC and Capillary Zone Electrophoresis Full article
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Journal of Analytical Chemistry
ISSN: 1061-9348 , E-ISSN: 1608-3199 |
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| Output data | Year: 2015, Volume: 70, Number: 6, Pages: 757-764 Pages count : 8 DOI: 10.1134/S1061934815060192 | ||
| Tags | capillary zone electrophoresis, HPLC, phosphomolybdates, polyoxometalates | ||
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Abstract:
A fundamental possibility of using ion-pair reversed-phased HPLC and capillary zone electrophoresis (CZE) for the study of polyoxometalate (POM) solutions has been demonstrated on an example of phosphovanadomolybdates of the composition [PVxMo12 − xO40]−(3 + x), where x = 1–3 and the possibility of the separation of the products of their synthesis has been shown. It has been found that the modification of the inner surface of a capillary by alkyl groups C1 and C8 results in an increase in the resolution of analytical signals in CZE. It has been shown that the results obtained by HPLC and CZE are in a good agreement and can be confirmed by the data of 51V NMR spectrometry.
Cite:
Zhdanov A.A.
, Shuvaeva O.V.
A Study of Complex Phosphovanadomolybdates [PVxMo12−xO40]−(3+x) by Reversed-Phase HPLC and Capillary Zone Electrophoresis
Journal of Analytical Chemistry. 2015. V.70. N6. P.757-764. DOI: 10.1134/S1061934815060192 WOS Scopus РИНЦ OpenAlex ANCAN
A Study of Complex Phosphovanadomolybdates [PVxMo12−xO40]−(3+x) by Reversed-Phase HPLC and Capillary Zone Electrophoresis
Journal of Analytical Chemistry. 2015. V.70. N6. P.757-764. DOI: 10.1134/S1061934815060192 WOS Scopus РИНЦ OpenAlex ANCAN
Original:
Жданов А.А.
, Шуваева О.В.
Исследование комплексных фосфованадомолибдатов [PVxMo12-xO40]-(3+x) методами обращенно-фазовой ВЭЖХ и капиллярного зонного электрофореза
Журнал аналитической химии. 2015. Т.70. №6. С.648-655. DOI: 10.7868/S0044450215060213 РИНЦ OpenAlex
Исследование комплексных фосфованадомолибдатов [PVxMo12-xO40]-(3+x) методами обращенно-фазовой ВЭЖХ и капиллярного зонного электрофореза
Журнал аналитической химии. 2015. Т.70. №6. С.648-655. DOI: 10.7868/S0044450215060213 РИНЦ OpenAlex
Dates:
| Submitted: | May 6, 2014 |
| Accepted: | Oct 1, 2014 |
| Published online: | May 26, 2015 |
| Published print: | Jun 1, 2015 |
Identifiers:
| ≡ Web of science: | WOS:000355178800017 |
| ≡ Scopus: | 2-s2.0-84930198945 |
| ≡ Elibrary: | 24036433 |
| ≡ OpenAlex: | W421549742 |
| ≡ Chemical Abstracts: | 2015:919919 |
| ≡ Chemical Abstracts (print): | 163:76090 |