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Application of POSS Nanotechnology for Preparation of Efficient Ni Catalysts for Hydrogen Production Full article

Journal Eurasian Chemico-Technological Journal
ISSN: 1562-3920
Output data Year: 2017, Volume: 19, Number: 1, Pages: 3-16 Pages count : 14 DOI: 10.18321/ectj497
Tags Autothermal reforming of methane, Hydrogen production, Nanomaterials, Ni nanoparticles, POSS nanotechnology
Authors Ismagilov I.Z. 1 , Matus E.V. 1 , Kuznetsov V.V. 1 , Yashnik S.A. 1 , Kerzhentsev M.A. 1 , Gerritsen G. 2 , Abbenhuis H.C.L. 2 , Ismagilov Z.R. 1,3
Affiliations
1 Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
2 Hybrid Catalysis B.V., Den Dolech 2, Eindhoven 5612, AZ, the Netherlands
3 Institute of Coal Chemistry and Material Science SB RAS, pr. Sovetskiy, 18, 650000, Kemerovo, Russia

Funding (2)

1 European Commission 262840 FP7-NMP-2010-LARGE-4 DEMCAMER
2 Federal Agency for Scientific Organizations 0303-2016-0004

Abstract: POSS (polyhedral oligomeric silsesquioxanes) nanotechnology was applied for preparation of efficient Ni catalysts for hydrogen production through autothermal reforming of methane (ATR of CH4). The novel metal-POSS precursor [Nickel (II) ‒ HeptaisobutylPOSS (C4H9)7Si7O9(OH)O2Ni] of Ni nanoparticles was introduced into Ce0.5Zr0.5O2 support with following calcination and reduction stages of activation. The peculiarity of the genesis of Ni/SiO2/Ce0.5Zr0.5O2 nanomaterials and their characteristics versus deposition mode were studied by X-ray fluorescence spectroscopy, thermal analysis, N2 adsorption, X-ray diffraction, high-resolution transmission electron microscopy and H2 temperature-programmed reduction. The two kinds of supported Ni-containing particles were observed: highly dispersed Ni forms (1‒2 nm) and large Ni-containing particles (up to 50‒100 nm in size). It was demonstrated that the textural, structural, red-ox and, consequently, catalytic properties of ex-Ni-POSS catalysts depend on the deposition mode. The increase of a portion of difficultly reduced Ni2+ species is found upon application of intermediate calcination during Ni-POSS deposition that has detrimental effect on the activity of catalyst in ATR of CH4. The Ni/SiO2/Ce0.5Zr0.5O2 catalyst prepared by one-step Ni-POSS deposition exhibits the highest H2 yield ‒ 80% at T = 800 °C.
Cite: Ismagilov I.Z. , Matus E.V. , Kuznetsov V.V. , Yashnik S.A. , Kerzhentsev M.A. , Gerritsen G. , Abbenhuis H.C.L. , Ismagilov Z.R.
Application of POSS Nanotechnology for Preparation of Efficient Ni Catalysts for Hydrogen Production
Eurasian Chemico-Technological Journal. 2017. V.19. N1. P.3-16. DOI: 10.18321/ectj497 WOS Scopus РИНЦ AN OpenAlex
Files: Full text from publisher
Dates:
Submitted: Aug 14, 2016
Accepted: Nov 28, 2016
Published print: Jan 25, 2017
Published online: Jun 19, 2017
Identifiers:
Web of science: WOS:000405987000001
Scopus: 2-s2.0-85025152094
Elibrary: 31100309
Chemical Abstracts: 2019:696909
OpenAlex: W2710519557
Citing:
DB Citing
Web of science 17
Scopus 15
Elibrary 16
OpenAlex 13
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