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Electrocatalysis of the Hydrogen Oxidation Reaction on Carbon-Supported Bimetallic NiCu Particles Prepared by an Improved Wet Chemical Synthesis Научная публикация

Журнал Journal of Electroanalytical Chemistry
ISSN: 1572-6657
Вых. Данные Год: 2016, Том: 783, Страницы: 146-151 Страниц : 6 DOI: 10.1016/j.jelechem.2016.11.031
Ключевые слова Alkaline solutions, Copper, Hydrogen oxidation reaction, Lyophilization, Nickel
Авторы Cherstiouk Olga V. 1,2 , Simonov Pavel A. 1,2 , Oshchepkov Alexandr G. 1,3,4 , Zaikovskii Vladimir I. 1,2 , Kardash Tatyana Yu. 1,2 , Bonnefont Antoine 3 , Parmon Valentin N. 1,2 , Savinova Elena R. 3
Организации
1 Boreskov Institute of Catalysis, Novosibirsk 630090, Russia
2 Novosibirsk State University, Novosibirsk 630090, Russia
3 Institut de Chimie de Strasbourg, UMR 7177 CNRS-University of Strasbourg, 67070 Strasbourg, France
4 Institut de Chimie et Procédés pour l'Energie, l'Environnement et la Santé, UMR 7515 CNRS-University of Strasbourg, 67087 Strasbourg Cedex, France

Информация о финансировании (1)

1 Федеральное агентство научных организаций России 0303-2015-0007

Реферат: Carbon supported Ni1 − xCux/C catalysts with different Ni:Cu atomic ratios comprising ca 30 nm particles uniformly distributed over the surface of carbon support were prepared by the incipient wetness impregnation followed by freeze-drying. The catalysts have been characterized by X-ray powder diffraction, transmission electron microscopy and cyclic voltammetry. The electrocatalytic activities of Ni1 − xCux/C catalysts in the hydrogen oxidation reaction in alkaline medium were examined with linear sweep voltammetry. It was found that addition of Cu at low fractions significantly improves the electrocatalytic activity of Ni in the hydrogen oxidation reaction, while increasing the Cu fraction above 5% results in its attenuation. The observed behavior of NiCu catalysts is compared to the literature data and tentatively explained by the influence of Cu on the energy of hydrogen adsorption on Ni.
Библиографическая ссылка: Cherstiouk O.V. , Simonov P.A. , Oshchepkov A.G. , Zaikovskii V.I. , Kardash T.Y. , Bonnefont A. , Parmon V.N. , Savinova E.R.
Electrocatalysis of the Hydrogen Oxidation Reaction on Carbon-Supported Bimetallic NiCu Particles Prepared by an Improved Wet Chemical Synthesis
Journal of Electroanalytical Chemistry. 2016. V.783. P.146-151. DOI: 10.1016/j.jelechem.2016.11.031 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 31 авг. 2016 г.
Принята к публикации: 14 нояб. 2016 г.
Опубликована online: 16 нояб. 2016 г.
Опубликована в печати: 15 дек. 2016 г.
Идентификаторы БД:
Web of science: WOS:000390627500020
Scopus: 2-s2.0-85002340227
РИНЦ: 29473440
Chemical Abstracts: 2016:1933851
Chemical Abstracts (print): 166:71220
OpenAlex: W2551233518
Цитирование в БД:
БД Цитирований
Web of science 63
Scopus 67
РИНЦ 60
OpenAlex 70
Альметрики: