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Active Species of Nonheme Iron and Manganese-Catalyzed Oxidations Обзор

Конференция IX International Conference “Mechanisms of Catalytic Reactions”
22-25 окт. 2012 , Санкт-Петербург
Журнал Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028
Вых. Данные Год: 2013, Том: 56, Номер: 11, Страницы: 939-949 Страниц : 11 DOI: 10.1007/s11244-013-0058-6
Ключевые слова Biomimetic oxidation, EPR, Iron, Manganese, Mechanism, Nonheme
Авторы Lyakin Oleg Y. 1 , Ottenbacher Roman V. 2 , Bryliakov Konstantin P. 1 , Talsi Evgenii P. 1
Организации
1 Siberian Branch of the Russian Academy of Sciences, Boreskov Institute of Catalysis, Pr. Lavrentieva 5, Novosibirsk 630090, Russian Federation
2 Novosibirsk State University, Ul. Pirogova 2, Novosibirsk 630090, Russian Federation

Информация о финансировании (3)

1 Российский фонд фундаментальных исследований 12-03-00782
2 Российский фонд фундаментальных исследований 12-03-31709
3 Российский фонд фундаментальных исследований 12-03-33180

Реферат: The intense catalytic and spectroscopic studies of the last decade provided important insights into the mechanisms of some nonheme iron-catalyzed oxidations with hydrogen peroxide. For manganese-based analogs, direct spectroscopic data on the structure of the reactive intermediates are scarce; mechanistic proposals are mainly based on catalytic studies and on analogy with iron systems. Herein, these data are summarized and contemporary mechanistic landscape is presented. We have mainly focused on iron and manganese complexes with N 4-donor aminopyridine ligands, which are one of the most successful catalysts for chemo-, regio- and enantioselective transformations of organic substrates with H2O2 and H2O2/CH3COOH as oxidants. The low-spin FeIII–OOH, FeIV = O and FeV = O species can be spectroscopically trapped in the catalyst systems studied, low-spin FeV = O intermediate being the most likely key oxidizing agent.
Библиографическая ссылка: Lyakin O.Y. , Ottenbacher R.V. , Bryliakov K.P. , Talsi E.P.
Active Species of Nonheme Iron and Manganese-Catalyzed Oxidations
Topics in Catalysis. 2013. V.56. N11. P.939-949. DOI: 10.1007/s11244-013-0058-6 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Опубликована online: 11 мая 2013 г.
Опубликована в печати: 1 авг. 2013 г.
Идентификаторы БД:
Web of science: WOS:000321664200011
Scopus: 2-s2.0-84880284086
РИНЦ: 20443689
Chemical Abstracts: 2013:745264
Chemical Abstracts (print): 159:141412
OpenAlex: W1972392045
Цитирование в БД:
БД Цитирований
Web of science 17
Scopus 21
РИНЦ 19
OpenAlex 21
Альметрики: