Reactions of Aromatic Compounds with Xenon Difluoride | Sciact - CRIS-system of Boreskov Institute of Catalysis

Reactions of Aromatic Compounds with Xenon Difluoride Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1070-4280 , E-ISSN: 1608-3393

Output data

Year: 2016, Volume: 52, Number: 10, Pages: 1400-1407 Pages count : 8 DOI: 10.1134/S1070428016100055

Tags

OXIDATIVE-FLUORINATION; POLYVALENT IODINE; BENZENE; DERIVATIVES; FLUORIDES; RESONANCE; CHEMISTRY; IONS; RING

Authors

Bardin V.V. ^1,2 , Adonin N.Yu. ^2,3

Affiliations

1	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090 Russia
2	Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090 Russia
3	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akad. Lavrent’eva 5, Novosibirsk 630090 Russia

Reactions of substituted benzenes C6H5R (R = Me, F, Cl, Br, CF3, NO2) with xenon difluoride in the presence of boron trifluoride–diethyl ether complex in weakly acidic (1,1,1,3,3-pentafluorobutane) and weakly basic media (acetonitrile) have been studied. These reactions lead to the formation of fluorobenzene derivatives FC6H4R (isomer mixture) together with isomeric difluorobenzenes and fluorinated and non-fluorinated biphenyls. The results have been compared with previously reported data obtained in other solvents using other catalysts.

Bardin V.V. , Adonin N.Y.
Reactions of Aromatic Compounds with Xenon Difluoride
Russian Journal of Organic Chemistry. 2016. V.52. N10. P.1400-1407. DOI: 10.1134/S1070428016100055 WOS Scopus РИНЦ AN OpenAlex

Бардин В.В. , Адонин Н.Ю.
О реакциях ароматических соединений с дифторидом ксенона
Журнал органической химии. 2016. Т.52. №10. С.1412-1419. РИНЦ

Submitted:	Apr 6, 2016
Published print:	Oct 1, 2016
Published online:	Nov 25, 2016

Web of science:	WOS:000388982200005
Scopus:	2-s2.0-84996479908
Elibrary:	27590032
Chemical Abstracts:	2016:1960493
OpenAlex:	W2557094839

DB	Citing
Web of science	2
Scopus	2
Elibrary	1
OpenAlex	2