Application of SR Methods for the Study of Nanocomposite Materials for Hydrogen Energy | Sciact - CRIS-system of Boreskov Institute of Catalysis

Application of SR Methods for the Study of Nanocomposite Materials for Hydrogen Energy Full article

Conference

The International Conference "Synchrotron and Free electron laser Radiation: generation and application"
04-07 Jul 2016 , Novosibirsk

Journal

Physics Procedia
ISSN: 1875-3892

Output data

Year: 2016, Volume: 84, Pages: 397-406 Pages count : 10 DOI: 10.1016/j.phpro.2016.11.068

Tags

catalytic membrane reactors, oxygen mobility, perovskite-fluorite nanocomposites, SOFC, synchrotron radiaton, unit cell volume relaxation, XAFS

Authors

Sadykov V.A. ^1,2 , Pavlova S.N. ¹ , Vinokurov Z.S. ^1,2 , Shmakov A.N. ^1,2,3 , Eremeev N.F. ^1,2 , Fedorova Yu.E. ^1,2,4 , Yakimchuk E.P. ¹ , Kriventsov V.V. ^1,3 , Bolotov V.A. ¹ , Tanashev Yu.Yu. ¹ , Sadovskaya E.M. ^1,2 , Cherepanova S.V. ¹ , Zolotarev K.V. ³

Affiliations

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk 630090, Russian Federation
2	Novosibirsk State University, Novosibirsk 630090, Russian Federation
3	Budker Institute of Nuclear Physics SB RAS, Novosibirsk 630090, Russian Federation
4	Novosibirsk State Pedagogical University, Novosibirsk 630126, Russian Federation

Funding (5)

1	Federal Agency for Scientific Organizations	V.44.1.17. (0303-2014-0003)
2	Russian Foundation for Basic Research	16-03-01139
3	European Commission	604296 FP7-NMP-2013-LARGE-7 BIOGO
4	Russian Science Foundation	14-50-00080
5	The Ministry of Education and Science of the Russian Federation	14.616.21.0036

This work summarizes results of synchrotron radiation (SR) studies of the real/defect structure of nanocrystalline/nanocomposite oxide materials, which determines their functional properties in hydrogen energy field as catalysts and mixed ionic electronic conductors (cathodes and anodes of solid oxide fuel cells, oxygen separation membranes). For nanocrystalline ceria-zirconia mixed oxide prepared via modified Pechini route using ethanol solution of reagents, a high spatial uniformity of cations distribution between domains along with the oxygen sublattice deficiency revealed by full-profile Rietveld refinement of SR diffraction data provide structure disordering enhancing oxygen mobility. For PrNi0.5Co0.5O3-δ – Ce0.9Y0.1O2-δ nanocomposite extensive transfer of Pr cations into fluorite domains generates a new path of fast oxygen diffusion along chains of Pr3+ – Pr4+ cations as directly proved by analysis of the unit cell relaxation after changing pO2 in perfect agreement with data obtained by oxygen isotope heteroexchange.

Sadykov V.A. , Pavlova S.N. , Vinokurov Z.S. , Shmakov A.N. , Eremeev N.F. , Fedorova Y.E. , Yakimchuk E.P. , Kriventsov V.V. , Bolotov V.A. , Tanashev Y.Y. , Sadovskaya E.M. , Cherepanova S.V. , Zolotarev K.V.
Application of SR Methods for the Study of Nanocomposite Materials for Hydrogen Energy

Physics Procedia. 2016. V.84. P.397-406. DOI: 10.1016/j.phpro.2016.11.068 WOS Scopus РИНЦ ANCAN OpenAlex

Full text from publisher

Published print:	Jan 1, 2016
Published online:	Dec 12, 2016

Web of science:	WOS:000392696400065
Scopus:	2-s2.0-85016242187
Elibrary:	29500786
Chemical Abstracts:	2016:2089598
Chemical Abstracts (print):	173:11437
OpenAlex:	W2565608234

DB	Citing
Web of science	10
Scopus	11
Elibrary	9
OpenAlex	9