Metal Dusting as a Route to Produce Active Catalyst for Processing Chlorinated Hydrocarbons into Carbon Nanomaterials | Sciact - CRIS-система Института катализа

Metal Dusting as a Route to Produce Active Catalyst for Processing Chlorinated Hydrocarbons into Carbon Nanomaterials Научная публикация

Конференция

IX International Conference “Mechanisms of Catalytic Reactions”
22-25 окт. 2012 , Санкт-Петербург

Журнал

Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028

Вых. Данные

Год: 2013, Том: 56, Номер: 11, Страницы: 1026-1032 Страниц : 7 DOI: 10.1007/s11244-013-0066-6

Ключевые слова

1,2-dichloroethane, Bulk metals and alloys, Carbon nanofibers, Chlorinated hydrocarbons, Metal dusting, NiCr alloy

Авторы

Mishakov Ilya V. ^1,2 , Bauman Yurii I. ¹ , Korneev Denis V. ³ , Vedyagin Aleksey A. ^1,2

Организации

1	Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
2	Novosibirsk State Technical University, Novosibirsk, Russia
3	State Research Center of Virology and Biotechnology ‘‘Vector’’, 630559 Koltsovo, Russia

Информация о финансировании (2)

1	Российский фонд фундаментальных исследований	12-03-31729
2	Президиум РАН	5.2.2

The interaction of 1,2-dichloroethane (DCE) vapors with bulk NiCr alloy resulting in complete metal wastage with the formation of carbon nanofibers (CNFs) has been described from mechanistic point of view. The genesis of surface transformations of the bulk NiCr alloy exposed to corrosive reaction mix Ar/H2/DCE at 550 °C was studied by AFM, SEM and TEM techniques. The mechanism of metal dusting in aggressive reaction media was suggested. The observed process has been considered as a way to produce the self-organizing Ni/CNF catalyst which is effective for further decomposition of chlorinated hydrocarbons leading to nanostructured carbon product.

Mishakov I.V. , Bauman Y.I. , Korneev D.V. , Vedyagin A.A.
Metal Dusting as a Route to Produce Active Catalyst for Processing Chlorinated Hydrocarbons into Carbon Nanomaterials
Topics in Catalysis. 2013. V.56. N11. P.1026-1032. DOI: 10.1007/s11244-013-0066-6 WOS Scopus РИНЦ CAPlusCA OpenAlex

Опубликована online:	24 мая 2013 г.
Опубликована в печати:	1 авг. 2013 г.

Web of science:	WOS:000321664200019
Scopus:	2-s2.0-84880420077
РИНЦ:	20443516
Chemical Abstracts:	2013:851865
Chemical Abstracts (print):	159:136606
OpenAlex:	W1963628298

БД	Цитирований
Web of science	33
Scopus	36
РИНЦ	41
OpenAlex	37