Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3-C4 Hydrocarbons Full article
Journal |
Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X |
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Output data | Year: 2017, Volume: 147, Number: 2, Pages: 310-317 Pages count : 8 DOI: 10.1007/s10562-016-1947-7 | ||||||
Tags | 1,3-Butadiene, 1-Butene, Concurrent reactions, Multicomponent bismuth molybdate, Oxidative dehydrogenation | ||||||
Authors |
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Affiliations |
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Funding (1)
1 | Federal Agency for Scientific Organizations | V.44.2.7. |
Abstract:
The influence of light hydrocarbons, such as n-butane, isobutane, propylene, cis- and trans-2-butenes, and isobutene on the oxidative dehydrogenation of 1-butene to 1,3-butadiene over BiMoKNiCoFePOx/SiO2 catalyst has been studied using a flow reactor. The inhibition effect of the listed hydrocarbons on the target reaction increased in the order of n-butane ~ isobutane < propylene < 2-butenes < isobutene. In addition, in contrast to 1-butene, isobutene has shown significant contribution to coke formation. It was suggested, that the coke formation and therefore the rate of the catalyst regeneration exercise a significant influence on the efficiency of 1-butene transformation into 1,3-butadiene in the concurrent presence of other hydrocarbons.
Cite:
Sobolev V.I.
, Koltunov K.Y.
, Zenkovets G.A.
Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3-C4 Hydrocarbons
Catalysis Letters. 2017. V.147. N2. P.310-317. DOI: 10.1007/s10562-016-1947-7 WOS Scopus РИНЦ ANCAN OpenAlex
Oxidative Dehydrogenation of 1-Butene to 1,3-Butadiene over a Multicomponent Bismuth Molybdate Catalyst: Influence of C3-C4 Hydrocarbons
Catalysis Letters. 2017. V.147. N2. P.310-317. DOI: 10.1007/s10562-016-1947-7 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: | Aug 22, 2016 |
Accepted: | Dec 6, 2016 |
Published online: | Dec 23, 2016 |
Published print: | Feb 1, 2017 |
Identifiers:
Web of science: | WOS:000394359600002 |
Scopus: | 2-s2.0-85007110527 |
Elibrary: | 29467583 |
Chemical Abstracts: | 2016:2172034 |
Chemical Abstracts (print): | 166:199140 |
OpenAlex: | W2560919641 |