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Chromatographic Properties PLOT Multicapillary Columns Full article

Journal Journal of Chromatography A
ISSN: 0021-9673 , E-ISSN: 1873-3778
Output data Year: 2017, Volume: 1488, Pages: 126-133 Pages count : 8 DOI: 10.1016/j.chroma.2017.01.087
Tags 1-vinylimidazole (VIm), Divinylbenzene (DVB), Gas-solid chromatography, Multicapillary column, PLOT column, Poly-(1-trimethylsilyl-1-propyne) (PTMSP)
Authors Nikolaeva O.A. 1,2 , Patrushev Y.V. 1,2 , Sidelnikov V.N. 1
Affiliations
1 Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk, 630090, Russia
2 Novosibirsk State University, Pirogova Str., 2, Novosibirsk, 630090, Russia

Abstract: Multicapillary columns (MCCs) for gas chromatography make it possible to perform high-speed analysis of the mixtures of gaseous and volatile substances at a relatively large amount of the loaded sample. The study was performed using PLOT MCCs for gas-solid chromatography (GSC) with different stationary phases (SP) based on alumina, silica and poly-(1-trimethylsilyl-1-propyne) (PTMSP) polymer as well as porous polymers divinylbenzene-styrene (DVB-St), divinylbenzene-vinylimidazole (DVB-VIm) and divinylbenzene-ethylene glycol dimethacrylate (DVB-EGD). These MCCs have the efficiency of 4000-10000 theoretical plates per meter (TP/m) and at a column length of 25–30 cm can separate within 10–20 s multicomponent mixtures of substances belonging to different classes of chemical compounds. The sample amount not overloading the column is 0.03–1 μg and depends on the features of a porous layer. Examples of separations on some of the studied columns are considered
Cite: Nikolaeva O.A. , Patrushev Y.V. , Sidelnikov V.N.
Chromatographic Properties PLOT Multicapillary Columns
Journal of Chromatography A. 2017. V.1488. P.126-133. DOI: 10.1016/j.chroma.2017.01.087 WOS Scopus РИНЦ ANCAN PMID OpenAlex
Dates:
Submitted: Nov 29, 2016
Accepted: Jan 30, 2017
Published online: Feb 1, 2017
Published print: Mar 10, 2017
Identifiers:
Web of science: WOS:000395853700014
Scopus: 2-s2.0-85011339772
Elibrary: 29476454
Chemical Abstracts: 2017:220725
Chemical Abstracts (print): 166:459842
PMID: 28173926
OpenAlex: W2584253675
Citing:
DB Citing
Web of science 26
Scopus 28
Elibrary 25
OpenAlex 28
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