Synthesis of Mesoporous Complex Framework Zirconium Phosphates via Organic-Inorganic Nanocomposites: Genesis of Structure, Adsorption and Catalytic Properties Научная публикация
| Конференция |
2003 MRS Fall Meeting 01-05 дек. 2003 , Boston |
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| Сборник | Continuous Nanophase and Nanostructured Materials: symposium held December 1-5, 2003, Boston, Massachusetts, USA (Materials Research Society symposium proceedings, Vol. 788) Сборник, Materials Research Society. Pennsylvania.2004. 686 c. ISBN 1107409349. |
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| Журнал |
MRS Online Proceedings Library
ISSN: 1946-4274 |
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| Вых. Данные | Год: 2003, Том: 788, Номер статьи : 1154, Страниц : 6 DOI: 10.1557/PROC-788-L11.54 | ||||||
| Ключевые слова | Adsorption; Adsorption isotherms; Catalysis; Fourier transform infrared spectroscopy; Mesoporous materials; Nanostructured materials; Organic acids; Phosphates; Positive ions; Synthesis (chemical) | ||||||
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Реферат:
This work presents the first results of synthesis of framework binary phosphates of zirconium and transition metal cations (Co, Cu, Ce) via nanocomposites of starting inorganic salts with citric acid and studies of their structure genesis. Nanoparticles of layered Zr phosphates with typical sizes in the range of 18-24 Ǻ are formed at the mixing stage. Less basic Cu and Co cations are mainly octa-coordinated with both phosphate groups of those nanoparticles and citric acid molecules. At subsequent thermal treatment, Cu and Co cations are incorporated within Zr phosphate nanoparticles acquiring a low coordination approaching a tetrahedral one while rearranging the nuclei structure into that of a framework type. Removal of citric acid by heating under air at 200—300o C preserves the size of nanoparticles while their ordered stacking forms mesoporous structure with a narrow pore size distribution ~ 50 Å and specific surface area up to 200 m2 /g after calcination at 600o C. The binary phosphates promoted by a small amount of Pt were found to be effective catalysts of NOx selective reduction by decane in the oxygen excess not subjected to coking with a high and stable performance at high space velocities in the presence of steam.
Библиографическая ссылка:
Frolova Y.V.
, Sadykov V.A.
, Pavlova S.N.
, Ven'yaminov S.A.
, Bunina R.V.
, Burgina E.B.
, Kolomiichuk V.N.
, Larina T.V.
, Mezentseva N.V.
, Fedotov M.A.
, Volodin A.M.
, Paukshtis E.A.
, Fenelonov V.B.
, Roy R.
, Agrawal D.
Synthesis of Mesoporous Complex Framework Zirconium Phosphates via Organic-Inorganic Nanocomposites: Genesis of Structure, Adsorption and Catalytic Properties
В сборнике Continuous Nanophase and Nanostructured Materials: symposium held December 1-5, 2003, Boston, Massachusetts, USA (Materials Research Society symposium proceedings, Vol. 788). – Materials Research Society., 2003. – C.215-220. – ISBN 1107409349. DOI: 10.1557/PROC-788-L11.54 Scopus РИНЦ РИНЦ CAPlusCA OpenAlex
Synthesis of Mesoporous Complex Framework Zirconium Phosphates via Organic-Inorganic Nanocomposites: Genesis of Structure, Adsorption and Catalytic Properties
В сборнике Continuous Nanophase and Nanostructured Materials: symposium held December 1-5, 2003, Boston, Massachusetts, USA (Materials Research Society symposium proceedings, Vol. 788). – Materials Research Society., 2003. – C.215-220. – ISBN 1107409349. DOI: 10.1557/PROC-788-L11.54 Scopus РИНЦ РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована в печати: | 1 янв. 2003 г. |
| Опубликована online: | 1 февр. 2011 г. |
Идентификаторы БД:
| Scopus: | 2-s2.0-2442646524 |
| РИНЦ: | 21463082 | 15037229 |
| Chemical Abstracts: | 2004:262962 |
| Chemical Abstracts (print): | 140:425707 |
| OpenAlex: | W2323446335 |