Crystal Structure of the Seven-Electron Molybdenum Custer [Mo3S4(dppe)3Cl3]∙3.5C4H8O2∙0.5Et2O Full article
| Journal |
Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2015, Volume: 56, Number: 4, Pages: 765-768 Pages count : 4 DOI: 10.1134/S002247661504023X | ||||
| Tags | cluster complexes, molybdenum, single crystal X-ray diffraction study, sulfur | ||||
| Authors |
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| Affiliations |
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Funding (4)
| 1 | Russian Foundation for Basic Research | 12-03-31530 (01201272367) |
| 2 | Russian Foundation for Basic Research | 12-03-33028 |
| 3 | Russian Foundation for Basic Research | 13-03-01088 |
| 4 | The Ministry of Education and Science of the Russian Federation |
Abstract:
The seven-electron neutral cluster complex [Mo3S4(dppe)3Cl3] (dppe = Ph2PCH2CH2PPh2) is obtained by the reduction of the [Mo3S4(dppe)3Cl3]Cl cluster with gallium metal. The molecular and crystal structure of [Mo3S4(dppe)3Cl3]∙3.5C4H8O2∙0.5Et2O solvate is determined by single crystal XRD. The crystallographic data are as follows: monoclinic crystal symmetry, space group C2/c, a = 41.1775(16) Å, b = 17.7178(7) Å, c = 28.9609(9) Å,
β = 110.363(1)°, V = 19808.7(13) Å3, Z = 8, dcalc = 1.384 g/cm3.
Cite:
Petrov P.A.
, Sosnin G.A.
, Naumov D.Y.
, Konchenko S.N.
Crystal Structure of the Seven-Electron Molybdenum Custer [Mo3S4(dppe)3Cl3]∙3.5C4H8O2∙0.5Et2O
Journal of Structural Chemistry. 2015. V.56. N4. P.765-768. DOI: 10.1134/S002247661504023X WOS Scopus РИНЦ ANCAN OpenAlex
Crystal Structure of the Seven-Electron Molybdenum Custer [Mo3S4(dppe)3Cl3]∙3.5C4H8O2∙0.5Et2O
Journal of Structural Chemistry. 2015. V.56. N4. P.765-768. DOI: 10.1134/S002247661504023X WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Петров П.А.
, Соснин Г.А.
, Наумов Д.Ю.
, Конченко С.Н.
Кристаллическая структура семиэлектронного кластера молибдена [Mo 3S 4(dppe) 3Cl 3]×3,5C 4H 8O 2×0,5Et 2O
Журнал структурной химии. 2015.
Т.56. №4. С.814-817. DOI: 10.15372/JSC201504023RSCI
РИНЦ
OpenAlex
Кристаллическая структура семиэлектронного кластера молибдена [Mo 3S 4(dppe) 3Cl 3]×3,5C 4H 8O 2×0,5Et 2O
Журнал структурной химии. 2015.
Т.56. №4. С.814-817. DOI: 10.15372/JSC201504023RSCI
РИНЦ
OpenAlex
Dates:
| Submitted: | May 30, 2014 |
| Published print: | Jul 1, 2015 |
| Published online: | Sep 27, 2015 |
Identifiers:
| Web of science: | WOS:000361897700023 |
| Scopus: | 2-s2.0-84942518556 |
| Elibrary: | 24953013 |
| Chemical Abstracts: | 2015:1564566 |
| Chemical Abstracts (print): | 164:446345 |
| OpenAlex: | W2467162835 |