Thermal Decomposition of Solid Solutions in Systems of Fe(II), Co(II), and Ni(II) Hydrogen Maleates with the Formation of Bimetallic Nanoparticles Full article
| Journal |
Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X |
||||||
|---|---|---|---|---|---|---|---|
| Output data | Year: 2017, Volume: 91, Number: 1, Pages: 136-140 Pages count : 5 DOI: 10.1134/S0036024417010320 | ||||||
| Tags | bimetallic nanoparticles, dehydration, solid solutions, thermal analysis, XRD phase analysis | ||||||
| Authors |
|
||||||
| Affiliations |
|
Abstract:
XRD phase analysis and thermal analysis are used to confirm the formation of a continuous series of solid solutions in which one cation is substituted for another in the systems Co(II) hydrogen maleate–Ni(II) hydrogen maleate; Fe(II) hydrogen maleate–Co(II) hydrogen maleate; and Fe(II) hydrogen maleate–Ni(II) hydrogen maleate. The unit cell volume of these solid solutions is shown to depend linearly on their composition. The linear character of changes in the initial temperatures of dehydration and thermal decomposition is established. Using the example of the first of these systems, it is shown that when heated, bimetallic nanoparticles embedded in the polymeric matrix of composites obtained via the thermal decomposition of solid solutions of hydrogen maleates undergo a second-order phase transition, resulting in decomposition of the solid solutions of metals at the Curie temperature.
Cite:
Yudanova L.I.
, Logvinenko V.A.
, Sheludyakova L.A.
, Ishchenko A.V.
, Rudina N.A.
Thermal Decomposition of Solid Solutions in Systems of Fe(II), Co(II), and Ni(II) Hydrogen Maleates with the Formation of Bimetallic Nanoparticles
Russian Journal of Physical Chemistry A. 2017. V.91. N1. P.136-140. DOI: 10.1134/S0036024417010320 WOS Scopus РИНЦ AN OpenAlex
Thermal Decomposition of Solid Solutions in Systems of Fe(II), Co(II), and Ni(II) Hydrogen Maleates with the Formation of Bimetallic Nanoparticles
Russian Journal of Physical Chemistry A. 2017. V.91. N1. P.136-140. DOI: 10.1134/S0036024417010320 WOS Scopus РИНЦ AN OpenAlex
Original:
Юданова Л.И.
, Логвиненко В.А.
, Шелудякова Л.А.
, Ищенко А.В.
, Рудина Н.А.
Термическое разложение твердых растворов в системах кислых малеатов Fe(II), Co(II) и Ni(II) с образованием биметаллических наночастиц
Журнал физической химии. 2017. Т.91. №1. С.136-140. DOI: 10.7868/S0044453717010320 РИНЦ OpenAlex
Термическое разложение твердых растворов в системах кислых малеатов Fe(II), Co(II) и Ni(II) с образованием биметаллических наночастиц
Журнал физической химии. 2017. Т.91. №1. С.136-140. DOI: 10.7868/S0044453717010320 РИНЦ OpenAlex
Dates:
| Submitted: | Dec 30, 2015 |
| Published print: | Jan 1, 2017 |
| Published online: | Feb 11, 2017 |
Identifiers:
| Web of science: | WOS:000394352300025 |
| Scopus: | 2-s2.0-85012226079 |
| Elibrary: | 29483770 |
| Chemical Abstracts: | 2017:250010 |
| OpenAlex: | W2586917083 |