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Oxidation of Metal Nanoparticles with the Grain Growth in the Oxide Научная публикация

Журнал Chemical Physics Letters
ISSN: 0009-2614 , E-ISSN: 1873-4448
Вых. Данные Год: 2017, Том: 674, Страницы: 136-140 Страниц : 5 DOI: 10.1016/j.cplett.2017.02.042
Ключевые слова Core-shell model, Diffusion, Grain growth, Nanoparticles, Oxidation kinetics
Авторы Zhdanov Vladimir P. 1,2
Организации
1 Department of Physics, Chalmers University of Technology, S-41296 Göteborg, Sweden
2 Boreskov Institute of Catalysis, Russian Academy of Sciences, Novosibirsk 630090, Russia

Реферат: Oxidation of metals can be influenced by the presence of electric field, lattice strain, rearrangement of the oxide structure, and formation of cracks in an oxide. The understanding of the interplay of these factors is still incomplete. We focus on the scenario including the oxide-grain growth. The model used implies that the whole process is limited by diffusion of metal or oxygen atoms along the grain boundaries as it was originally proposed by Fehlner and Mott for macroscopic samples. For nanoparticles, the model predicts a transition from the power-law oxide growth at low conversion to slower growth at high conversion.
Библиографическая ссылка: Zhdanov V.P.
Oxidation of Metal Nanoparticles with the Grain Growth in the Oxide
Chemical Physics Letters. 2017. V.674. P.136-140. DOI: 10.1016/j.cplett.2017.02.042 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 22 янв. 2017 г.
Принята к публикации: 13 февр. 2017 г.
Опубликована online: 16 февр. 2017 г.
Опубликована в печати: 1 апр. 2017 г.
Идентификаторы БД:
Web of science: WOS:000397696600022
Scopus: 2-s2.0-85013968894
РИНЦ: 29489314
Chemical Abstracts: 2017:430361
Chemical Abstracts (print): 166:381151
OpenAlex: W2589112144
Цитирование в БД:
БД Цитирований
Web of science 5
Scopus 5
РИНЦ 5
OpenAlex 6
Альметрики: