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Methanol Synthesis from Industrial CO2 Sources: A Contribution to Chemical Energy Conversion Научная публикация

Журнал Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X
Вых. Данные Год: 2017, Том: 147, Номер: 2, Страницы: 416 - 427 Страниц : 12 DOI: 10.1007/s10562-016-1960-x
Ключевые слова Activation energy < elementary kinetics, Benzene impurities, Carbon dioxide, Methanol synthesis, Stability
Авторы Bukhtiyarova Marina 1 , Lunkenbein Thomas 2 , Kähler Kevin 1 , Schlögl Robert 1,2
Организации
1 Max Planck Institute for Chemical Energy Conversion, Stiftstrasse 34 – 36, 45470 Mülheim a.d. Ruhr, Germany
2 Fritz Haber Institute, Max Planck Society, Faradayweg 4 – 6, 14195 Berlin, Germany

Информация о финансировании (1)

1 Max Planck Society

Реферат: CO2 hydrogenation as a route for the chemical energy storage over a commercial Cu/ZnO/Al2O3 catalyst has been studied. To check the optimal conditions for an efficient methanol production the influence of temperature and space velocity on the catalytic performance has been demonstrated. Time-on-stream measurements in the absence and the presence of benzene in the gas feed mixture were performed to investigate the possibility to use alternative carbon sources, which contain traces of aromatics. The catalyst can operate in a stable way without the presence of carbon monoxide in the feed, which means that increased water contents in the product gas cannot destroy the catalyst’s performance completely. The presence of benzene in the feed does not lead to a deactivation of the catalyst. With these findings methanol production starting from exhaust gases from steel mills seems to become an interesting alternative for sustainable methanol production
Библиографическая ссылка: Bukhtiyarova M. , Lunkenbein T. , Kähler K. , Schlögl R.
Methanol Synthesis from Industrial CO2 Sources: A Contribution to Chemical Energy Conversion
Catalysis Letters. 2017. V.147. N2. P.416 - 427. DOI: 10.1007/s10562-016-1960-x WOS Scopus РИНЦ CAPlusCA OpenAlex
Файлы: Полный текст от издателя
Даты:
Поступила в редакцию: 8 нояб. 2016 г.
Принята к публикации: 15 дек. 2016 г.
Опубликована online: 16 янв. 2017 г.
Опубликована в печати: 1 февр. 2017 г.
Идентификаторы БД:
Web of science: WOS:000394359600013
Scopus: 2-s2.0-85009494317
РИНЦ: 29588351
Chemical Abstracts: 2017:122011
Chemical Abstracts (print): 166:210750
OpenAlex: W2574961121
Цитирование в БД:
БД Цитирований
Web of science 104
Scopus 116
OpenAlex 122
Альметрики: