The Origin of Self-Sustained Reaction-Rate Oscillations in the Oxidation of Methane over Nickel: An Operando XRD and Mass Spectrometry Study Full article
| Journal |
Catalysis Science and Technology
ISSN: 2044-4753 , E-ISSN: 2044-4761 |
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| Output data | Year: 2017, Volume: 7, Pages: 1646-1649 Pages count : 4 DOI: 10.1039/C6CY02673G | ||||||
| Tags | CATALYTIC-OXIDATION; BEHAVIOR; PROPANE | ||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0001 |
Abstract:
The self-sustained kinetic oscillations in the catalytic oxidation of methane over Ni foil have been studied at atmospheric pressure using an X-ray diffraction technique and mass spectrometry. It has been shown that the regular reaction-rate oscillations appear under oxygen-deficient conditions and the period of oscillations varies between approximately 200 and 4000 s. The operando measurements have revealed a higher activity of metallic Ni in the reaction than NiO oxide and have unambiguously showed that the oscillations arise due to the reversible bulk oxidation of Ni to NiO.
Cite:
Saraev A.A.
, Vinokurov Z.S.
, Kaichev V.V.
, Shmakov A.N.
, Bukhtiyarov V.I.
The Origin of Self-Sustained Reaction-Rate Oscillations in the Oxidation of Methane over Nickel: An Operando XRD and Mass Spectrometry Study
Catalysis Science and Technology. 2017.
V.7. P.1646-1649. DOI: 10.1039/C6CY02673G
WOS
Scopus
РИНЦ
AN
OpenAlex
The Origin of Self-Sustained Reaction-Rate Oscillations in the Oxidation of Methane over Nickel: An Operando XRD and Mass Spectrometry Study
Catalysis Science and Technology. 2017.
V.7. P.1646-1649. DOI: 10.1039/C6CY02673G
WOS
Scopus
РИНЦ
AN
OpenAlex
Files:
Full text from publisher
Dates:
| Submitted: | Dec 24, 2016 |
| Accepted: | Mar 23, 2017 |
| Published online: | Mar 23, 2017 |
| Published print: | Apr 21, 2017 |
Identifiers:
| Web of science: | WOS:000399919200002 |
| Scopus: | 2-s2.0-85022098636 |
| Elibrary: | 31052998 |
| Chemical Abstracts: | 2017:477882 |
| OpenAlex: | W2598464360 |