Kinetic Studies of Methanol Dehydrogenation. Part II: Copper on Silica-Montmorillonite Composite Научная публикация
| Журнал |
Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204 |
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| Вых. Данные | Год: 2017, Том: 121, Номер: 2, Страницы: 403-412 Страниц : 10 DOI: 10.1007/s11144-017-1191-1 | ||||
| Ключевые слова | Copper catalysts, Kinetics, Methanol dehydrogenation, Methyl formate, Rate constants, Silica–montmorillonite composite | ||||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Федеральное агентство научных организаций России | 0303-2016-0014 |
| 2 | Российский фонд фундаментальных исследований | 16-38-00095 |
Реферат:
The kinetics of methanol dehydrogenation over copper catalyst supported on silica–montmorillonite composite was studied. The samples of the catalyst were prepared by incipient wetness impregnation followed by drying, calcination and reduction in hydrogen flow in a temperature range 200–400 °C. Kinetic studies were performed in a flow fixed-bed reactor. Observed rate constants were determined for the reactions of methanol dehydrogenation into methyl formate and methyl formate decomposition on carbon monoxide and hydrogen. An increase in the reduction temperature was shown to have no significant effect on the catalytic properties. Numerical methods were used to calculate the kinetic constants with consideration of reversibility of methanol dehydrogenation reaction the sample reduced at 300 °C.
Библиографическая ссылка:
Shelepova E.V.
, Ilina L.Y.
, Vedyagin A.A.
Kinetic Studies of Methanol Dehydrogenation. Part II: Copper on Silica-Montmorillonite Composite
Reaction Kinetics, Mechanisms and Catalysis. 2017. V.121. N2. P.403-412. DOI: 10.1007/s11144-017-1191-1 WOS Scopus РИНЦ CAPlus OpenAlex
Kinetic Studies of Methanol Dehydrogenation. Part II: Copper on Silica-Montmorillonite Composite
Reaction Kinetics, Mechanisms and Catalysis. 2017. V.121. N2. P.403-412. DOI: 10.1007/s11144-017-1191-1 WOS Scopus РИНЦ CAPlus OpenAlex
Даты:
| Поступила в редакцию: | 13 апр. 2017 г. |
| Принята к публикации: | 18 апр. 2017 г. |
| Опубликована online: | 26 апр. 2017 г. |
| Опубликована в печати: | 1 авг. 2017 г. |
Идентификаторы БД:
| Web of science: | WOS:000405582300003 |
| Scopus: | 2-s2.0-85018261096 |
| РИНЦ: | 31030082 |
| Chemical Abstracts: | 2017:677333 |
| OpenAlex: | W2610124041 |