A Microfiber Catalyst with Lemniscate Structural Elements Full article
Journal |
Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555 |
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Output data | Year: 2017, Volume: 9, Number: 1, Pages: 39-47 Pages count : 9 DOI: 10.1134/S207005041701010X | ||||||||
Tags | catalyst, glass-fiber fabric, mass transfer, microfibers, oxidation, platinum | ||||||||
Authors |
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Affiliations |
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Funding (2)
1 | Federal Agency for Scientific Organizations | V.46.5.6. |
2 | Novosibirsk National Research University |
Abstract:
A new type of catalyst based on microfiber supports with microfibers twined into looped threads (lemniscate) that in turn form a structured flexible stable and geometrically regular bulk bed permeable to a reaction flow and not requiring any additional structurial elements is described. Deep toluene oxidation experiments show that the proposed platinum lemniscate glass-fiber catalyst (LGFC) considerably surpasses (by 8–10 times and more) familiar geometric types of catalysts, microfiber and otherwise, in both the specific observed activity per unit active component mass and the ratio between the observed activity and the specific hydraulic resistance. The reason for its superiority is a uniquely high efficiency of mass transfer in the external diffusion region of reactions. Among the promising fields of application for the proposed systems are fast gasphase catalytic reactions, liquid-phase catalytic reactions, and complicated reaction processes, in which the selectivity and the yield of target products are sensitive to diffusion inhibition.
Cite:
Lopatin S.A.
, Mikenin P.E.
, Pisarev D.A.
, Zazhigalov S.V.
, Baranov D.V.
, Zagoruiko A.N.
A Microfiber Catalyst with Lemniscate Structural Elements
Catalysis in Industry. 2017. V.9. N1. P.39-47. DOI: 10.1134/S207005041701010X WOS Scopus РИНЦ OpenAlex
A Microfiber Catalyst with Lemniscate Structural Elements
Catalysis in Industry. 2017. V.9. N1. P.39-47. DOI: 10.1134/S207005041701010X WOS Scopus РИНЦ OpenAlex
Original:
Лопатин С.А.
, Микенин П.Е.
, Писарев Д.А.
, Зажигалов С.В.
, Баранов Д.В.
, Загоруйко А.Н.
Микроволокнистый катализатор с лемнискатными структурными элементами
Катализ в промышленности. 2016. Т.16. №5. С.35-42. DOI: 10.18412/1816-0387-2016-5-35-42 РИНЦ OpenAlex
Микроволокнистый катализатор с лемнискатными структурными элементами
Катализ в промышленности. 2016. Т.16. №5. С.35-42. DOI: 10.18412/1816-0387-2016-5-35-42 РИНЦ OpenAlex
Dates:
Submitted: | Aug 2, 2016 |
Published print: | Jan 1, 2017 |
Published online: | Apr 7, 2017 |
Identifiers:
Web of science: | WOS:000423241100006 |
Scopus: | 2-s2.0-85017179270 |
Elibrary: | 29490030 |
OpenAlex: | W2530361849 |