Intermetallic Compounds as Potential Alternatives to Noble Metals in Heterogeneous Catalysis: The Partial Hydrogenation of Butadiene on γ-Al4Cu9(1 1 0) | Sciact - CRIS-system of Boreskov Institute of Catalysis

Intermetallic Compounds as Potential Alternatives to Noble Metals in Heterogeneous Catalysis: The Partial Hydrogenation of Butadiene on γ-Al4Cu9(1 1 0) Full article

Journal

ChemCatChem
ISSN: 1867-3880 , E-ISSN: 1867-3899

Output data

Year: 2017, Volume: 9, Number: 12, Pages: 2292-2296 Pages count : 5 DOI: 10.1002/cctc.201601587

Tags

aluminum, copper, heterogeneous catalysis, hydrogenation, surface chemistry

Authors

Piccolo Laurent ¹ , Kibis Lidiya ^2,3 , De Weerd Marie-Cécile ⁴ , Gaudry Emilie ⁴ , Ledieu Julian ⁴ , Fournée Vincent ⁴

Affiliations

1	Univ Lyon, Universit Claude Bernard—Lyon 1 CNRS, IRCELYON—UMR 5256 2 Avenue Albert Einstein, F-69626 Villeurbanne Cedex (France)
2	Boreskov Institute of Catalysis SB RAS Lavrentieva 5, Novosibirsk 630090 (Russia)
3	Novosibirsk State University Pirogova St. 2, Novosibirsk 630090 (Russia)
4	Institut Jean Lamour,UMR 7198 CNRS & Universit de Lorraine Parc de Saurupt, CS 50840, F-54011 Nancy (France)

Funding (1)

French Embassy in Moscow

Recently, non-noble intermetallic compounds have shown promising catalytic performances in the partial hydrogenation of alkynes and alkenes. In this work, the properties of γ-Al4Cu9(1 1 0) toward the gas-phase hydrogenation of butadiene were investigated at total pressures of 2–20 mbar and temperatures of 110–180 °C. The model catalyst is active and 100 % selective to butenes. Moreover, although less active than Al13Fe4(0 1 0), which was evaluated previously for the same reaction, it is more selective and more stable. The combination of catalytic tests with pre- and postreaction Auger electron spectroscopy measurements and comparative tests with Cu(1 1 0) shows that Cu governs the reaction on γ-Al4Cu9(1 1 0). However, the lower activity of the (more Cu-rich) sputtered Al4Cu9 surface with respect to the annealed one and the differences between Al4Cu9 and Cu surfaces in terms of butene isomer distribution, butene conversion kinetics, and sensitivity to poisons, demonstrate the unique character of the intermetallic compound.

Piccolo L. , Kibis L. , De Weerd M-C. , Gaudry E. , Ledieu J. , Fournée V.
Intermetallic Compounds as Potential Alternatives to Noble Metals in Heterogeneous Catalysis: The Partial Hydrogenation of Butadiene on γ-Al4Cu9(1 1 0)
ChemCatChem. 2017. V.9. N12. P.2292-2296. DOI: 10.1002/cctc.201601587 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Dec 6, 2016
Accepted:	Jan 31, 2017
Published online:	Apr 6, 2017
Published print:	Jun 22, 2017

Web of science:	WOS:000412338800029
Scopus:	2-s2.0-85017352771
Elibrary:	31030652
Chemical Abstracts:	2017:577323
OpenAlex:	W2583823001

DB	Citing
Web of science	7
Scopus	8
Elibrary	8
OpenAlex	8