Design of Anodes for IT SOFC: Effect of Complex Oxide Promoters and Pd on Activity and Stability in Methane Steam Reforming of Ni/YSZ (ScSZ) Cermets | Sciact - CRIS-система Института катализа

Design of Anodes for IT SOFC: Effect of Complex Oxide Promoters and Pd on Activity and Stability in Methane Steam Reforming of Ni/YSZ (ScSZ) Cermets Научная публикация

Конференция

2006 MRS Fall Meeting: Symposium AA - Solid-State Ionics-2006
27 нояб. - 1 дек. 2006 , Boston, MA

Сборник

Solid-State Ionics-2006 : symposium held November 27 - December 1, 2006, Boston, Massachusetts, USA
Сборник, Materials Research Society. Pennsylvania.2007. 422 c. ISBN 978-1-55899-929-9.

Журнал

MRS Online Proceedings Library
ISSN: 1946-4274

Вых. Данные

Год: 2006, Том: 972, Номер статьи : 306, Страниц : 6 DOI: 10.1557/PROC-0972-AA03-06

Ключевые слова

Composite materials; Crystal atomic structure; Doping (additives); Energy dispersive spectroscopy; Oxidation; Transmission electron microscopy

Авторы

Sadykov Vladislav A. ¹ , Mezentseva Natalia V. ² , Bunina Rimma V. ² , Alikina Galina M. ² , Lukashevich Anton I. ² , Rogov Vladimir A. ² , Moroz Ella M. ² , Zaikovskii Vladimir I. ² , Ishchenko Arcady ² , Bobrenok Oleg F. ³ , Smirnova Alevtina ⁴ , Irvine John ⁵ , Vasylyev Oleksandr ⁶

Организации

1	Heterogeneous catalysis, Boreskov Institute of Catalysis, pr. Lavrentieva, 5, Novosibirsk, 630090, Russian Federation
2	Boreskov Institute of Catalysis, Novosibirsk, 630090, Russian Federation
3	Institute of Thermophysics SB RAS, Novosibirsk, 630090, Russian Federation
4	University of Connecticut, Storrs, CT, 06269
5	University of St Andrews, Fife, KY169ST, United Kingdom
6	Institute for Problems of Materials Science, Kyiv, 03142, Ukraine

Информация о финансировании (2)

1	Сибирское отделение Российской академии наук	95
2	North Atlantic Treaty Organization	SfP-980878

Effect of fluorite-like or perovskite-like complex oxide promoters and Pd on the performance of Ni/YSZ and Ni/ScSZ cermets in methane steam reforming or selective oxidation by O2 into syngas at short contact times was studied. Spatial uniformity of dopants distribution in composites was controlled by TEM combined with EDX, while the lattice oxygen mobility and reactivity was elucidated by CH4 and H2 TPR. Oxide promoters allow to operate even at stoichiometric H2O/CH4 ratio by suppressing coke deposition through modification of Ni surface, while doping by Pd ensures reasonable performance at moderate (∼550 °C) temperatures required for Intermediate–Temperature Solid Oxide Fuel Cells (IT SOFC).

Sadykov V.A. , Mezentseva N.V. , Bunina R.V. , Alikina G.M. , Lukashevich A.I. , Rogov V.A. , Moroz E.M. , Zaikovskii V.I. , Ishchenko A. , Bobrenok O.F. , Smirnova A. , Irvine J. , Vasylyev O.
Design of Anodes for IT SOFC: Effect of Complex Oxide Promoters and Pd on Activity and Stability in Methane Steam Reforming of Ni/YSZ (ScSZ) Cermets
В сборнике Solid-State Ionics-2006 : symposium held November 27 - December 1, 2006, Boston, Massachusetts, USA. – Materials Research Society., 2006. – C.205-210. – ISBN 978-1-55899-929-9. DOI: 10.1557/PROC-0972-AA03-06 WOS Scopus РИНЦ CAPlusCA OpenAlex

Опубликована в печати:	1 янв. 2006 г.
Опубликована online:	26 февр. 2011 г.

Web of science:	WOS:000246435400029
Scopus:	2-s2.0-34250852219
РИНЦ:	15051870
Chemical Abstracts:	2007:489373
Chemical Abstracts (print):	147:98456
OpenAlex:	W2049658408

БД	Цитирований
Web of science	1
Scopus	6
РИНЦ	6
OpenAlex	4