Sciact
  • EN
  • RU

Doped Nanocrystalline Pt-Promoted Ceria-Zirconia as Anode Catalysts for IT-SOFC: Synthesis and Properties Full article

Conference 2007 MRS Spring Meeting. Symposium JJ - Functional Nanoscale Ceramics for Energy Systems
09-13 Apr 2007 , San Francisco, CA
Journal MRS Online Proceedings Library
ISSN: 1946-4274
Output data Year: 2007, Volume: 1023, Article number : 207, Pages count : 6 DOI: 10.1557/PROC-1023-JJ02-07
Tags Catalysis; Catalyst activity; Ceramic materials; Cerium alloys; Cerium compounds; Gadolinium; Isotopes; Nanostructured materials; Oxygen; Platinum; Steam engineering; Surface properties; Surface structure; Zirconia
Authors Sadykov Vladislav 1 , Mezentseva Natalia 1 , Alikina Galina 1 , Lukashevich Anton 1 , Muzykantov Vitalii 1 , Bunina Rimma 1 , Boronin Andrei 1 , Pazhetnov Egor 1 , Paukshtis Eugenii 1 , Kriventsov Vladimir 1 , Smirnova Alevtina 2 , Vasylyev Oleksandr 3 , Irvine John 4 , Bobrenok Oleg 5 , Voronin Vladimir 6 , Berger Ivan 6
Affiliations
1 Boreskov Institute of Catalysis, Novosibirsk, 630090, Russian Federation
2 Global Fuel Cells Center, University of Connecticut, Storrs, CT, CT
3 Institute for Problems of Materials Science, Kiev, 142, Ukraine
4 School of Chemistry, University of St Andrews, St Andrews, KY16 9ST, United Kingdom
5 Institute of Thermophysics SB RAS, Novosibirsk, 630090, Russian Federation
6 Institute of Metals Physics UB RAS, Yekaterinburg, 234005, Russian Federation

Funding (5)

1 North Atlantic Treaty Organization SfP-980878
2 International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union 05-1000005-7663
3 International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union YSF 06-1000014-5773
4 Russian Foundation for Basic Research 05-03-34761
5 Siberian Branch of the Russian Academy of Sciences 95

Abstract: Ceria-zirconia samples doped with Gd, Pr, Sm, or La cations were prepared via Pechini route and promoted by Pt. Effect of their real structure and surface properties (characterized by neutronography, EXAFS, XPS, FTIRS of adsorbed CO) on the mobility and reactivity of the lattice oxygen (by oxygen isotope exchange and CH4 TPR) was analyzed. For the reaction of CH4 steam reforming (SR), catalytic performance is determined both by Pt dispersion and lattice oxygen mobility. Ni-YSZ anodes promoted by these catalysts possess a stable and efficient performance in CH4 SR in the 600-800°C range in stoichiometric feeds without coking.
Cite: Sadykov V. , Mezentseva N. , Alikina G. , Lukashevich A. , Muzykantov V. , Bunina R. , Boronin A. , Pazhetnov E. , Paukshtis E. , Kriventsov V. , Smirnova A. , Vasylyev O. , Irvine J. , Bobrenok O. , Voronin V. , Berger I.
Doped Nanocrystalline Pt-Promoted Ceria-Zirconia as Anode Catalysts for IT-SOFC: Synthesis and Properties
MRS Online Proceedings Library. 2007. V.1023. 207 :1-6. DOI: 10.1557/PROC-1023-JJ02-07 Scopus РИНЦ РИНЦ ANCAN OpenAlex
Dates:
Published print: Jan 1, 2007
Published online: Feb 1, 2011
Identifiers:
Scopus: 2-s2.0-70349914427
Elibrary: 15292657 | 51691993
Chemical Abstracts: 2008:112704
Chemical Abstracts (print): 149:13321
OpenAlex: W2160119893
Citing:
DB Citing
Scopus 16
Elibrary 23
OpenAlex 12
Altmetrics: