Iron-Containing Materials as Catalysts for the Synthesis of 1,5-Benzodiazepine from 1,2-Phenylenediamine and Acetone | Sciact - CRIS-система Института катализа

Iron-Containing Materials as Catalysts for the Synthesis of 1,5-Benzodiazepine from 1,2-Phenylenediamine and Acetone Научная публикация

Журнал

Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204

Вых. Данные

Год: 2017, Том: 121, Номер: 2, Страницы: 689-699 Страниц : 11 DOI: 10.1007/s11144-017-1190-2

Ключевые слова

1,2-Phenylenediamine, 1,5-Benzodiazepine, Acetone, Fe-containing mesoporous materials, Fe-VSB-5

Авторы

Timofeeva Maria N. ^1,2 , Prikhod’ko Sergey A. ¹ , Makarova Kristina N. ^1,2 , Malyshev Mikhail E. ¹ , Panchenko Valentina N. ^1,2 , Ayupov Artem B. ¹ , Jhung Sung Hwa ³

Организации

1	Boreskov Institute of Catalysis SB RAS, Prospekt Akad. Lavrentieva 5, 630090 Novosibirsk, Russian Federation
2	Novosibirsk State Technical University, Prospekt K. Marksa 20, 630092 Novosibirsk, Russian Federation
3	Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Sankyuck-Dong, Buk-Ku, Daegu 41566, Republic of Korea

Информация о финансировании (3)

1	Федеральное агентство научных организаций России	0303-2016-0002
2	Федеральное агентство научных организаций России	0303-2016-0007
3	Kyungpook National University

The cyclocondensation of 1,2-phenylenediamine (I) with acetone was investigated in the presence of Fe-containing microporous nickel phosphate molecular sieves (Fe-VSB-5) and Fe-containing mesoporous mesophase materials (Fe-MMM). The main product was 2,3-dihydro-2,2,4-trimethyl-1H-1,5-benzodiazepine (1,5-benzodiazepine) with 86–88% yield at 50 °C, with an acetone/(I) molar ratio of 2.5 in methanol as the reaction medium. The Fe content was found to affect not only the reaction rate but also yield of 1,5-benzodiazepine. The high reaction rate and yield of 1,5-benzodiazepine were—achieved with isolated iron sites in frameworks of Fe-VSB-5 and Fe-MMM.

Timofeeva M.N. , Prikhod’ko S.A. , Makarova K.N. , Malyshev M.E. , Panchenko V.N. , Ayupov A.B. , Jhung S.H.
Iron-Containing Materials as Catalysts for the Synthesis of 1,5-Benzodiazepine from 1,2-Phenylenediamine and Acetone
Reaction Kinetics, Mechanisms and Catalysis. 2017. V.121. N2. P.689-699. DOI: 10.1007/s11144-017-1190-2 WOS Scopus РИНЦ CAPlus OpenAlex

Поступила в редакцию:	6 мар. 2017 г.
Принята к публикации:	13 апр. 2017 г.
Опубликована online:	28 апр. 2017 г.
Опубликована в печати:	1 авг. 2017 г.

Web of science:	WOS:000405582300021
Scopus:	2-s2.0-85018267591
РИНЦ:	31037804
Chemical Abstracts:	2017:684718
OpenAlex:	W2610015008

БД	Цитирований
Web of science	10
Scopus	11
РИНЦ	15
OpenAlex	13