Selective Deoxygenation of Vegetable Oils in the Presence of Pt–Sn/Al2O3 Catalyst | Sciact - CRIS-system of Boreskov Institute of Catalysis

Selective Deoxygenation of Vegetable Oils in the Presence of Pt–Sn/Al2O3 Catalyst Full article

Journal

Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171

Output data

Year: 2015, Volume: 64, Number: 9, Pages: 2062-2068 Pages count : 7 DOI: 10.1007/s11172-015-1118-9

Tags

biofuel, green diesel, heterogeneous catalysis, microalgal oil, platinum, tin, vegetable oil

Authors

Tsodikov M.V. ^1,2 , Chistyakov A.V. ^1,2 , Gubanov M.A. ^1,2 , Zharova P.A. ^1,2 , Shapovalov S.S. ³ , Pasynskii A.A. ³ , Kriventsov V.V. ⁴ , Moiseev I.I. ^1,3

Affiliations

1	A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninsky prosp., 119991 Moscow, Russian Federation
2	Moscow Institute of Physics and Technology, 9 Institutskii per., 141700 Dolgoprudny, Moscow region, Russian Federation.
3	Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991 Moscow, Russian Federation
4	Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrentieva, 630090 Novosibirsk, Russian Federation

Funding (1)

The Ministry of Education and Science of the Russian Federation

14.575.21.0052 (RFMEFI57514X0052) (114103040071)

We studied deoxygenation of individual fatty esters and fatty acid triglycerides from vegetable oils and lipid extracts from microalgae in the presence of catalysts prepared by deposition of Pt–Sn-containing compounds onto the γ-aluminum oxide surface. Using individual esters as an example, selective reduction of oxygen into water was demonstrated for the first time to proceed on a catalytic system at the 5 : 1 molar ratio of Sn and Pt active components to afford hydrocarbon components of substrates in virtually quantitative yield. Transformation of vegetable oil in the presence of this catalyst affords the C3–C18 hydrocarbon fraction in yield up to 99% at the content of C3 and C18 hydrocarbons up to 90%. The fraction of C1 and C2 hydrocarbons and carbon oxides is not higher than 0.5%. The possibility of carbon weight loss minimization during transformation of lipids was shown for the first time.

Tsodikov M.V. , Chistyakov A.V. , Gubanov M.A. , Zharova P.A. , Shapovalov S.S. , Pasynskii A.A. , Kriventsov V.V. , Moiseev I.I.
Selective Deoxygenation of Vegetable Oils in the Presence of Pt–Sn/Al2O3 Catalyst
Russian Chemical Bulletin. 2015. V.64. N9. P.2062-2068. DOI: 10.1007/s11172-015-1118-9 WOS Scopus РИНЦ ANCAN OpenAlex

Цодиков М.В. , Чистяков А.В. , Губанов М.А. , Жарова П.А. , Шаповалов С.С. , Пасынский А.А. , Кривенцов В.В. , Моисеев И.И.
Селективная деоксигенация растительных масел в присутствии катализатора Pt-Sn/Al2O3
Известия Академии наук. Серия химическая. 2015. Т.64. №9. С.2062-2068. РИНЦ

Submitted:	Apr 13, 2015
Published print:	Sep 1, 2015
Published online:	Sep 27, 2016

Web of science:	WOS:000383958300008
Scopus:	2-s2.0-84988727195
Elibrary:	27568024
Chemical Abstracts:	2016:1577843
Chemical Abstracts (print):	166:30823
OpenAlex:	W2525446915

DB	Citing
Web of science	10
Scopus	13
Elibrary	12
OpenAlex	10