Structured Catalysts for Biofuels Transformation into Syngas with Active Components Based on Perovskite and Spinel Oxides Supported on Mg-Doped Alumina | Sciact - CRIS-система Института катализа

Structured Catalysts for Biofuels Transformation into Syngas with Active Components Based on Perovskite and Spinel Oxides Supported on Mg-Doped Alumina Научная публикация

Конференция

International Symposium on Catalytic Conversion of Energy and Resources
30 июн. - 2 июл. 2016 , Seoul

Журнал

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Вых. Данные

Год: 2017, Том: 293-294, Страницы: 176-185 Страниц : 10 DOI: 10.1016/j.cattod.2017.05.055

Ключевые слова

Biofuels, Catalysis, Coking stability, Nanocomposites, Syngas

Авторы

Sadykov Vladislav ^1,2 , Pavlova Svetlana ¹ , Smal Ekaterina ¹ , Arapova Marina ^1,3 , Simonov Mikhail ^1,2 , Mezentseva Natalia ^1,2 , Rogov Vladimir ^1,2 , Glazneva Tatiana ^1,2 , Lukashevich Anton ¹ , Roger Anne-Cecile ³ , Parkhomenko Ksenia ³ , van Veen Andre ⁴ , Smorygo Oleg ⁵

Организации

1	Boreskov Institute of catalysis, Novosibirsk, Russia
2	Novosibirsk State University, Novosibirsk, Russia
3	University of Strasbourg, Strasbourg, France
4	University of Warwick, Warwick, UK
5	Powder Metallurgy Institute, Minsk, Belarus

Информация о финансировании (3)

1	European Commission	604296 FP7-NMP-2013-LARGE-7 BIOGO
2	Федеральное агентство научных организаций России	0303-2016-0013
3	Российский фонд фундаментальных исследований	12-03-93115

For structured catalysts of biofuels transformation into syngas inexpensive and stable to sintering active components based upon Mg-doped γ-alumina with supported LaNi0.9Ru0.1O3 perovskite or MnCr2O4 spinel promoted by Ru + Ni were developed. Characterization of the surface features, reactivity, catalytic activity and routes of ethanol transformation on these catalysts demonstrated that suppression of support acidity, strong interaction of Ru-Ni alloy nanoparticles with manganese chromite layers on support and a high redox ability provide a high yield of syngas and stability to coking. The most promising active component (2 wt% Ni + 2 wt% Ru)/MnCr2O4/10 wt% MgO − γ-Al2O3 supported on microchannel heat-conducting CrAlO cermet plates demonstrated a high performance and stability to coking in the autothermal reforming of such reactive fuels as glycerol, anisol and turpentine oil.

Sadykov V. , Pavlova S. , Smal E. , Arapova M. , Simonov M. , Mezentseva N. , Rogov V. , Glazneva T. , Lukashevich A. , Roger A-C. , Parkhomenko K. , van Veen A. , Smorygo O.
Structured Catalysts for Biofuels Transformation into Syngas with Active Components Based on Perovskite and Spinel Oxides Supported on Mg-Doped Alumina
Catalysis Today. 2017. V.293-294. P.176-185. DOI: 10.1016/j.cattod.2017.05.055 WOS Scopus РИНЦ CAPlusCA OpenAlex

Поступила в редакцию:	19 авг. 2016 г.
Принята к публикации:	13 мая 2017 г.
Опубликована online:	31 мая 2017 г.
Опубликована в печати:	1 сент. 2017 г.

Web of science:	WOS:000405047100024
Scopus:	2-s2.0-85020022597
РИНЦ:	29762359
Chemical Abstracts:	2017:886344
Chemical Abstracts (print):	167:280468
OpenAlex:	W2617930271

БД	Цитирований
Web of science	16
Scopus	17
РИНЦ	18
OpenAlex	17